87214-07-1Relevant articles and documents
Synthesis of P-chirogenic diarylphosphinoacetic acids and their proline derivatives for palladium-catalysed allylic alkylation reactions
Lam, Hubert,Horton, Peter N.,Hursthouse, Michael B.,Aldous, David J.,King, Kuok Hii
, p. 8145 - 8148 (2007/10/03)
The synthesis of P-chirogenic diarylphosphinocarboxylic acids was achieved, from which a new class of amido- and amino-diphosphine ligands (PNP*) were derived, containing an L-proline backbone. The catalytic activities of the novel ligands were evaluated
A flexible, highly efficient method for the preparation of homochiral oxazaphospholidine-boranes
Sheehan, Susan Kult,Jiang, Meiqun,McKinstry, Lydia,Livinghouse, Tom,Garton, Donna
, p. 6155 - 6162 (2007/10/02)
An efficient and operationally simple procedure for the synthesis of 2-substituted 3,4-dimethyl-5-phenyloxazaphospholidine derivatives has been developed. This new method permits the large scale preparation of a range of electronically and sterically diff
Asymmetric synthesis of phosphinates, phosphine oxides and phosphines by Michaelis Arbuzov rearrangement of chiral oxazaphospholidine
Juge, S.,Genet, J. P.
, p. 2783 - 2786 (2007/10/02)
A general approach to asymmetric synthesis of high optically active tertiary organophosphorus compounds is described.Oxazaphospholidine 3 reacts with alkyl halide to give regio and stereoselectively the corresponding phosphinamide 4.Methyl phenyl phosphin