851096-55-4

Basic information

• Product Name: Benzene, 1-methoxy-2-methyl-4-[[(2E)-6-methyl-2,5-heptadienyl]oxy]-
• CAS NO: 851096-55-4
• Molecular Formula: C16H22O2
• Molecular Weight: 246.349
• Mol File: 851096-55-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-2-methyl-4-[[(2E)-6-methyl-2,5-heptadienyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-2-methyl-4-[[(2E)-6-methyl-2,5-heptadienyl]oxy]-(851096-55-4)
• EPA Substance Registry System: Benzene, 1-methoxy-2-methyl-4-[[(2E)-6-methyl-2,5-heptadienyl]oxy]-(851096-55-4)

Safety Data

• Hazardous Substances Data: 851096-55-4(Hazardous Substances Data)

Upstream product

• 14786-82-4 4-hydroxy-2-methylanisole 
• 51007-22-8 (2E)-6-methylhepta-2,5-dien-1-ol 
• 13522-78-6 4-methoxy-3-methylphenyl acetate 
• 10024-90-5 4-methoxy-3-methylacetophenone 
• 578-58-5 2-methylmethoxybenzene 
• 870-63-3 prenyl bromide 
• 119614-32-3 6-methylhept-5-en-2-yn-1-ol 

Downstream Products

• 1398244-32-0 (3S,5R)-2-(2,3-dihydroxy-2-methylhept-6-en-5-yl)-5-methylcyclohexa-2,5-diene-1,4-dione 
• 851096-53-2 2-[1-(3,3-dimethyl-oxiranylmethyl)-allyl]-4-methoxy-5-methyl-phenol 
• 851096-54-3 4-methoxy-5-methyl-2-(6-methylhepta-1,5-dien-3-yl)phenol 

Relevant articles and documents

Total synthesis of (-)-heliespirone a and (+)-heliespirone C

Total syntheses of the spiro-epimeric natural products (-)-heliespirone A and (+)-heliespirone C are described. The successful strategy involved an aromatic Claisen rearrangement, a diastereoselective Sharpless asymmetric dihydroxylation (AD) reaction, and an intramolecular oxa-Michael addition.

Total synthesis of (±)-heliannuol C and E via aromatic Claisen rearrangement

The total synthesis of heliannuol C and E from a common intermediate are described. Key steps in the synthesis include a regioselective aromatic Claisen rearrangement to install the (1-vinyl)-4-methyl-3-pentenyl substituent and regioselective biomimetic 7