853955-64-3Relevant articles and documents
Carboallylation of electron-deficient alkenes by palladium/copper catalysis
Semba, Kazuhiko,Ohta, Naoki,Yano, Yuko,Nakao, Yoshiaki
supporting information, p. 11463 - 11466 (2018/10/20)
A method for the carboallylation of electron-deficient alkenes with tetraorganosilicon reagents and allylic carbonates based on Pd/Cu catalysis has been developed. This method affords a wide range of structurally diverse carbon skeletons from readily available starting materials, and tolerates various functional groups.
Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes: An entry to tetraorganosilicon reagents for the silicon-based cross-coupling reaction
Nakao, Yoshiaki,Imanaka, Hidekazu,Sahoo, Akhila K.,Yada, Akira,Hiyama, Tamejiro
, p. 6952 - 6953 (2007/10/03)
Alkenyl- and aryl[2-(hydroxymethyl)phenyl]dimethylsilanes, highly stable tetraorganosilicon reagents, are found to react with aryl and alkenyl iodides in the presence of a palladium catalyst and K2CO3 as a base, significantly milder conditions compared with those ever reported for the silicon-based cross-coupling reactions. The reaction tolerates a wide range of functional groups, including silyl protectors, and allows a gram-scale synthesis to recover and reuse the silicon residue. Copyright
