858468-00-5

Basic information

• Product Name: 1,2,3-trimethoxy-5-(prop-1-en-2-yl)benzene
• Synonyms: 1,2,3-trimethoxy-5-(prop-1-en-2-yl)benzene
• CAS NO: 858468-00-5
• Molecular Weight: 208.257
• Mol File: 858468-00-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1,2,3-trimethoxy-5-(prop-1-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3-trimethoxy-5-(prop-1-en-2-yl)benzene(858468-00-5)
• EPA Substance Registry System: 1,2,3-trimethoxy-5-(prop-1-en-2-yl)benzene(858468-00-5)

Safety Data

• Hazardous Substances Data: 858468-00-5(Hazardous Substances Data)

Upstream product

• 75-24-1 trimethylaluminum 
• 1136-86-3 methyl (3,4,5-trimethoxyphenyl) ketone 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 917-64-6 methyl magnesium iodide 
• 1916-07-0 3,4,5-trimethoxybenzoic acid methyl ester 
• 2675-79-8 1-bromo-3,4,5-trimethoxybenzene 
• 108-22-5 Isopropenyl acetate 

Downstream Products

• 127033-98-1 (E)-3-phenyl-1-(3,4,5-trimethoxyphenyl)prop-2-en-1-one 
• 1136-86-3 methyl (3,4,5-trimethoxyphenyl) ketone 

Relevant articles and documents

Formal Allylation and Enantioselective Cyclopropanation of Donor/Acceptor Rhodium(II) Azavinyl Carbenes

A highly efficient formal allylation of dihydronaphthotriazoles with alkenes under rhodium(II) catalysis is reported. Various allyl dihydronaphthalene derivatives were furnished via rhodium(II) azavinyl carbenes with moderate to good yields and excellent chemoselectivity. When monosubstituted alkenes are used, cyclopropanation occurs and good to excellent enantioselectivities have been achieved. Particularly noteworthy is the allylic C(sp2)-H activation instead of traditional C(sp3)-H activation in the formal allylation process.

Cobalt-Catalyzed Cross-Couplings between Alkenyl Acetates and Aryl or Alkenyl Zinc Pivalates

CoBr2 (5 mol %) in the presence of 2,2′-bipyridyl (5 mol %) enables electrophilic alkenylations between easily accessible alkenyl acetates or tosylates and various functionalized aryl zinc pivalates at ambient temperature. This cobalt-catalyzed

Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents

Iron-catalyzed acyloxyalkylation of styrene derivatives using hypervalent iodine reagents was achieved. The acyloxyalkylation reaction proceeded using various types of styrenes and hypervalent iodine reagents. The acyloxyalkylated products were obtained in moderate to good yields without loss of the functional groups. The reaction proceeded via the formation of radical species derived from hypervalent iodine reagents by decarboxylation.