85920-92-9

Basic information

• Product Name: 4-Oxo-4-phenyl-2-phenylsulfanyl-butyric acid methyl ester
• Synonyms: 4-Oxo-4-phenyl-2-phenylsulfanyl-butyric acid methyl ester
• CAS NO: 85920-92-9
• Molecular Weight: 300.378
• Mol File: 85920-92-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4-Oxo-4-phenyl-2-phenylsulfanyl-butyric acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Oxo-4-phenyl-2-phenylsulfanyl-butyric acid methyl ester(85920-92-9)
• EPA Substance Registry System: 4-Oxo-4-phenyl-2-phenylsulfanyl-butyric acid methyl ester(85920-92-9)

Safety Data

• Hazardous Substances Data: 85920-92-9(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 14090-83-6 methyl 2-phenylsulfinylacetate 
• 85920-99-6 methyl 2-chloro-2-(phenylsulfanyl)acetate 

Downstream Products

• 14274-07-8 methyl 3-benzoylacrylate 
• 25333-24-8 3-benzoylpropionic acid methyl ester 
• 14274-07-8 methyl trans-β-benzoylacrylate 

Relevant articles and documents

STANNOUS (II) TRIFLATE PROMOTED REARRANGEMENT OF β-KETO SULFOXIDES. SYNTHESIS OF 1,4-DIKETONES

Stannous triflate promotes rearrangement of β-keto sulfoxides to generate α-thiocarbocation, which in turn react with silyl enol ethers to give 2-arylsulfenyl-1,4-diketones in good yields.

A REGIOSPECIFIC SYNTHESIS OF γ-KETO ESTERS: THE ALKYLATION OF O-SILYLATED ENOLATES WITH METHYL α-CHLORO-α-PHENYLTHIOACETATE

Methyl α-chloro-α-phenylthio acetate (2) regiospecifically alkylates O-silylated enolates to form γ-keto esters.