861215-70-5

Basic information

• Product Name: Benzenesulfonyl chloride, 4-(2,3,4,5,6,7,8,9-octahydro-1,8-dioxo-1H-xanthen-9-yl)-
• CAS NO: 861215-70-5
• Molecular Formula: C19H17ClO5S
• Molecular Weight: 392.86
• Mol File: 861215-70-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenesulfonyl chloride, 4-(2,3,4,5,6,7,8,9-octahydro-1,8-dioxo-1H-xanthen-9-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonyl chloride, 4-(2,3,4,5,6,7,8,9-octahydro-1,8-dioxo-1H-xanthen-9-yl)-(861215-70-5)
• EPA Substance Registry System: Benzenesulfonyl chloride, 4-(2,3,4,5,6,7,8,9-octahydro-1,8-dioxo-1H-xanthen-9-yl)-(861215-70-5)

Safety Data

• Hazardous Substances Data: 861215-70-5(Hazardous Substances Data)

Upstream product

• 184955-27-9 1,1'-dihydroxy-2,2'-(phenylmethylene)bis(cyclohex-1-ene)-3,3'-dione 
• 100-52-7 benzaldehyde 
• 504-02-9 1,3-cylohexanedione 
• 95200-84-3 9-phenyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione 

Relevant articles and documents

Chlorosulfonation of 9-aryloctahydroxanthen-1,8-diones

The 9-aryloctahydroxanthen-1,8-diones (3, 4-24) were prepared by reaction of cyclohexan-1,3-dione (1) with selected arylaldehydes. The xanthendiones (4-9, 11, 12, 18, 21, 22) were successfully reacted with chlorosulfonic acid, and the crude sulfonyl chlorides were converted into 15 sulfonamides (26-40) for screening as potential pesticides. Attempted chlorosulfonation of the xanthendiones (13-17) was unsuccessful. α-Methylcinnamaldehyde was reacted with cyclohexandione (1) to yield the corresponding xanthendione derivative (23). On the other hand, with o-methoxycinnamaldehyde an impure product formed and the p-methoxy isomer afforded the corresponding 2-arylpyran (25). The NMR spectral data of the compounds are briefly discussed.