86505-47-7

Basic information

• Product Name: 2-Cyclopenten-1-one, 3-methyl-2-[(4-methylphenyl)sulfinyl]-, (S)-
• CAS NO: 86505-47-7
• Molecular Formula: C13H14O2S
• Molecular Weight: 234.319
• Mol File: 86505-47-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Cyclopenten-1-one, 3-methyl-2-[(4-methylphenyl)sulfinyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclopenten-1-one, 3-methyl-2-[(4-methylphenyl)sulfinyl]-, (S)-(86505-47-7)
• EPA Substance Registry System: 2-Cyclopenten-1-one, 3-methyl-2-[(4-methylphenyl)sulfinyl]-, (S)-(86505-47-7)

Safety Data

• Hazardous Substances Data: 86505-47-7(Hazardous Substances Data)

Upstream product

• 1087267-75-1 (3aS,6aS,S_S)-6a-[(4-methylphenyl)sulfinyl]-3a,4,5,6a-tetrahydrocyclopenta[c]pyrazol-6(3H)-one 
• 79681-26-8 2-[(S)-(4-methylphenyl)sulfinyl]cyclopent-2-en-1-one 
• 18107-18-1 diazomethyl-trimethyl-silane 

Downstream Products

• 86505-48-8 (R)-3-methyl-3-(p-tolyl)cyclopentan-1-one 
• 65564-92-3 (S)-(-)-3-methyl-3-(4-methylphenyl)cyclopentanone 
• 1087267-78-4 (3aR,6aR,S_S)-3a-methyl-6a-[(4-methylphenyl)sulfinyl]-3a,4,5,6a-tetrahydrocyclopenta[c]pyrazol-6(3H)-one 
• 1087267-81-9 (3aS,6aS,S_S)-3a-methyl-6a-[(4-methylphenyl)sulfinyl]-3a,4,5,6a-tetrahydrocyclopenta[c]pyrazol-6(3H)-one 

Relevant articles and documents

Synthesis of bicyclo[3.1.0]hexanones via 1,3-dipolar cycloaddition of diazoalkanes to homochiral α-sulfinyl-2-cyclopentenones

The reactions of diazomethane, diazoethane, and (trimethylsilyl)diazomethane with (S)-2-p-tolylsulfinylcyclopent-2-en-1-one have been studied. The sulfinyl group increases the reactivity and controls the π-facial and endo/exo selectivities. The π-facial s