87109-43-1

Basic information

• Product Name: 1,3-Dioxolane, 2-methyl-2-(4-phenyl-3-butenyl)-, (E)-
• CAS NO: 87109-43-1
• Molecular Formula: C14H18O2
• Molecular Weight: 218.296
• Mol File: 87109-43-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,3-Dioxolane, 2-methyl-2-(4-phenyl-3-butenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2-methyl-2-(4-phenyl-3-butenyl)-, (E)-(87109-43-1)
• EPA Substance Registry System: 1,3-Dioxolane, 2-methyl-2-(4-phenyl-3-butenyl)-, (E)-(87109-43-1)

Safety Data

• Hazardous Substances Data: 87109-43-1(Hazardous Substances Data)

Upstream product

• 33599-88-1 (E)-6-phenylhex-5-en-2-one 
• 107-21-1 ethylene glycol 
• 87109-34-0 2-diphenylphosphinoyl-4-(2-methyl-[1,3]dioxolan-2-yl)-1-phenyl-butan-1-one 
• 87109-17-9 1-diphenylphosphinoyl-4-(2-methyl-[1,3]dioxolan-2-yl)-propane 
• 5978-08-5 1-chloro-4-(1,3-dioxolane)-n-pentane 
• 87109-24-8 5-diphenylphosphinoyl-6-hydroxy-6-phenylhexan-2-one ethylene acetal 
• 24108-29-0 3-(2-methyl-[1,3]dioxolan-2-yl)-propionaldehyde 
• 1080-32-6 O,O-diethyl benzylphosphonate 
• 3695-28-1 5-iodo-2-pentanone ethylene ketal 
• 517-23-7 3-acetyl-2-oxo-4,5-dihydrofuran 
• 5891-21-4 5-chloro-2-pentanone 
• 24400-75-7 ethylene-cetal de la bromo-5 pentanone-2 
• 3884-71-7 bromo-5-pentanone-2 
• 3695-29-2 5-iodo-2-pentanone 

Relevant articles and documents

Catalytic, Enantioselective Syn-Oxyamination of Alkenes

The chemo-, regio-, diastereo-, and enantioselective 1,2-oxyamination of alkenes using selenium(II/IV) catalysis with a chiral diselenide catalyst is reported. This method uses N-tosylamides to generate oxazoline products that are useful both as protected

SYNTHESIS OF SINGLE ISOMERS (E OR Z) OF PROTECTED γ,δ-UNSATURATED KETONES BY THE HORNER-WITTIG REACTION

The lithium derivative of the γ-diphenylphosphinoyl ketal (10a) added to aldehydes and ketones to give stable Horner-Wittig intermediates (11) which were separated and converted into single isomers (E or Z) or γ,δ-unsaturated ketals (12). erythro-Adducts (11) and hence Z-(12), were selectively formed by addition of aldehydes and threo adducts (11), and hence E-(12), by reduction of the corresponding α-diphenylphosphinoyl ketones (13), prepared by acylation of the same γ-diphenylphosphinoyl ketal (10a).