87258-61-5

Basic information

• Product Name: (S)-(+)-3-p-methoxyphenyl-1-phenylbutan-1-one
• Synonyms: (S)-(+)-3-p-methoxyphenyl-1-phenylbutan-1-one
• CAS NO: 87258-61-5
• Molecular Weight: 254.329
• Mol File: 87258-61-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (S)-(+)-3-p-methoxyphenyl-1-phenylbutan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(+)-3-p-methoxyphenyl-1-phenylbutan-1-one(87258-61-5)
• EPA Substance Registry System: (S)-(+)-3-p-methoxyphenyl-1-phenylbutan-1-one(87258-61-5)

Safety Data

• Hazardous Substances Data: 87258-61-5(Hazardous Substances Data)

Upstream product

• 1125576-35-3 (R)-N-(1-(4-methoxyphenyl)ethyl)-4-methyl-benzenesulfonamide 
• 614-20-0 3-oxo-3-phenylpropionic acid 
• 35660-91-4 (E)-1-phenyl-2-buten-1-one 
• 5720-07-0 4-methoxyphenylboronic acid 
• 108454-55-3 3-(4-methoxyphenyl)-2-butenoic acid ethyl ester 
• 1354197-48-0 (E)-3-(4-methoxyphenyl)-1-phenylbut-2-en-1-one 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 98-86-2 acetophenone 
• 495-41-0 1-phenylbut-2-en-1-one 
• 1376710-73-4 (E)-N-methoxy-3-(4-methoxyphenyl)-N-methylbut-2-enamide 
• 99142-77-5 methyl (E)-3-(3-methoxyphenyl)-3-methylacrylate 
• 70-11-1 α-bromoacetophenone 
• 87305-45-1 (R,S)-NN-dimethyl-N-phenacyl-1-p-methoxyphenylethylammonium bromide 
• 50640-96-5 (R,S)-NN-dimethyl-1-p-methoxyphenylethylamine 

Relevant articles and documents

Compartmentalization and Photoregulating Pathways for Incompatible Tandem Catalysis

This contribution describes an advanced compartmentalized micellar nanoreactor that possesses a reversible photoresponsive feature and its application toward photoregulating reaction pathways for incompatible tandem catalysis under aqueous conditions. The

Lewis Base-Catalyzed Enantioselective Conjugate Reduction of β,β-Disubstituted α,β-Unsaturated Ketones with Trichlorosilane: E/ Z-Isomerization, Regioselectivity, and Synthetic Applications

The chiral bisphosphine dioxide-catalyzed asymmetric conjugate reduction of acyclic β,β-disubstituted α,β-unsaturated ketones with trichlorosilane affords saturated ketones having a stereogenic carbon center at the carbonyl β-position with high enantioselectivities. Because the E/Z-isomerizations of enone substrates occur concomitantly, reduction products with the same absolute configurations are obtained from either (E)- or (Z)-enones. Conjugate reduction is accelerated in the presence of an electron-rich aryl group at the β-position of the enone owing to its carbocation-stabilizing ability. Computational studies were also conducted in order to elucidate the origin of the observed enantioselectivity. The regio- and enantioselective reductions of dienones were realized and applied to the syntheses of ar-turmerone, turmeronol A, mutisianthol, and jungianol, which are optically active sesquiterpenes.

Highly efficient synthesis of chiral aromatic ketones: Via Rh-catalyzed asymmetric hydrogenation of β,β-disubstituted enones

A succinct and efficient protocol was developed for the synthesis of chiral aromatic ketones via asymmetric hydrogenation of β,β-disubstituted enones with rhodium catalysts based on chiral bisphosphine thiourea ligands. A series of substrates (17 examples) was smoothly catalyzed to afford the corresponding chiral aromatic ketones in high conversions (>99%) with excellent enantioselectivities (up to 96% ee).