87829-01-4

Basic information

• Product Name: Benzoic acid, 4-[(phenylhydrazono)methyl]-, methyl ester
• CAS NO: 87829-01-4
• Molecular Formula: C15H14N2O2
• Molecular Weight: 254.288
• Mol File: 87829-01-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-[(phenylhydrazono)methyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-[(phenylhydrazono)methyl]-, methyl ester(87829-01-4)
• EPA Substance Registry System: Benzoic acid, 4-[(phenylhydrazono)methyl]-, methyl ester(87829-01-4)

Safety Data

• Hazardous Substances Data: 87829-01-4(Hazardous Substances Data)

Upstream product

• 6908-41-4 4-(methoxycarbonyl)benzyl alcohol 
• 62-53-3 aniline 
• 100-63-0 phenylhydrazine 
• 1571-08-0 methyl 4-formylbenzoate 
• 619-66-9 4-Carboxybenzaldehyde 
• 623-24-5 1,4-bis(bromomethyl)benzene 
• 72358-76-0 phenylhydrazine acetate 

Downstream Products

• 1014625-49-0 4-(1-phenyl-5-p-tolyl-1H-pyrazol-3-yl)-benzoic acid methyl ester 
• 1016169-25-7 4-(1-phenyl-4-p-tolyl-1H-pyrazol-3-yl)-benzoic acid methyl ester 
• 1016169-26-8 4-(5-amino-1-phenyl-4-p-tolyl-1H-pyrazol-3-yl)-benzoic acid methyl ester 
• 1016169-27-9 4-(3-nitro-1-phenylazo-2-p-tolyl-propyl)-benzoic acid methyl ester 
• 1310486-83-9 methyl 4-(1-benzyl-1H-benzo[d]imidazole-2-yl)benzoate 
• 1376268-22-2 dimethyl 4,4'-(2-phenyl-2H-1,2,3-triazole-4,5-diyl) dibenzoate 
• 1571-08-0 methyl 4-formylbenzoate 
• 1447058-46-9 3-(p-methoxycarbonylphenyl)-1,5-diphenylformazan 
• 1447058-49-2 1-o-nitrophenyl-3-(p-methoxycarbonylphenyl)-5-phenylformazan 
• 1447058-53-8 1-m-nitrophenyl-3-(p-methoxycarbonylphenyl)-5-phenylformazan 
• 1447058-56-1 1-p-nitrophenyl-3-(p-methoxycarbonylphenyl)-5-phenylformazan 
• 1447058-59-4 1-o-tolyl-3-(p-methoxycarbonylphenyl)-5-phenylformazan 
• 1447058-63-0 1-m-tolyl-3-(p-methoxycarbonylphenyl)-5-phenylformazan 
• 1447058-67-4 1-p-tolyl-3-(p-methoxycarbonylphenyl)-5-phenylformazan 

Relevant articles and documents

Synthesis, spectral analysis, structural elucidation and quantum chemical studies of (E)-methyl-4-[(2-phenylhydrazono)methyl]benzoate

The title compound, (E)-methyl-4-[(2-phenylhydrazono)methyl]benzoate, (I), (C15H14N2O2), has been synthesized by condensation reaction of methyl-4-formylbenzoate and phenylhydrazine. The compound has been charac

Experimental and quantum chemical studies of the structural and spectral properties of novel diazenyl formazans

A new series of 3-(p-substitutedphenyl)-5-phenyl-1-(4-phenyldiazenyl)phenylformazans were synthesized by coupling p-substituted phenyl or pyridinylhydrazones with p-aminoazobenzene diazonium chloride. All compounds were characterized by FT-IR, UV–Vis, 1H NMR, and 13C NMR spectroscopic techniques, and HR-MS. DFT was used to calculate the molecular structures and 1H and 13C chemical shift values of the synthesized compounds with PBE1PBE functional and 6-311G(2d,2p)basis set combination. The IR spectra of the novel formazans were calculated using DFT at PBE1PBE/6-311G(d,p)level of theory. The electronic absorption spectra of the optimized structures were evaluated by TD-DFT method at PBE1PBE/6-311G(2d,2p)level of theory. The absorption spectra of the synthesized diazenyl formazans were investigated in three different solvents. A good correlation was established between the experimental data and calculated results.

Ion-pairing catalysis in the enantioselective addition of hydrazones to N-acyldihydropyrrole derivatives

We have demonstrated that dihydropyrrole-based enamide derivatives can act as efficient precursors of chiral quaternary N-acyliminium salts under Br?nsted acid catalysis that undergo reactions with hydrazones, the latter participating as masked nucleophilic carbonyl group equivalents. The optimized methodology provides a variety of enantiopure α-substituted proline derivatives in excellent yields, being even compatible with disubstituted β-enamides that generate two contiguous stereocentres.