88-11-9Relevant articles and documents
Synthesis of Carbamic Esters Derivatives of Itols: Antifungal Activity against Various Crop Diseases
Len, Christophe,Postel, Denis,Ronco, Gino,Villa, Pierre,Goubert, Christel,Jeufrault, Eric,Mathon, Bernard,Simon, Herve
, p. 3 - 6 (1997)
-
Method for preparing substituted thiophenol and heterocyclic thiophenol by continuous flow reactor
-
Paragraph 0045-0047; 0051-0053; 0057-0059; 0063-0095, (2019/01/14)
The invention relates to a method for preparing substituted thiophenol and heterocyclic thiophenol by a continuous flow reactor. Phenol and phenol derivatives or heterocyclic phenol are taken as starting materials, and target compounds are prepared by four-step reactions of chlorination, esterification, rearrangement and hydrolysis, wherein the rearrangement reaction is conducted in the continuousflow reactor. According to the method, the reaction is guaranteed by a miniaturized heating device for high-temperature reaction and heat generated by the reaction, the conversion rate and the yieldhigher than those in the conventional reactor are obtained in the short residence time of tens of seconds, relevant side reactions are reduced, meanwhile, fluctuation of temperature and concentrationis avoided in the reaction process, temperature run-away and overheat are avoided, and the reaction process is safe and controllable.
SYNTHESIS OF N,N-DIALKYLCHLOROTHIOFORMAMIDES AND THEIR REACTIONS WITH PHOSPHOROUS ACID ESTERS
Pudovik, A. N.,Khairullin, V. K.,Vasyanina, M. A.
, p. 1328 - 1331 (2007/10/02)
-