881376-69-8

Basic information

• Product Name: 3,5-di-tert-butylbenzene-1,2-diol
• Synonyms: 3,5-DI(TERT-BUTYL)BENZENE-1,2-DIOL
• CAS NO: 881376-69-8
• Molecular Formula: C14H22O2
• Molecular Weight: 222.32
• Mol File: 881376-69-8.mol
• Article Data: 60

Chemical Properties

• Boiling Point: 309.7 °C at 760 mmHg
• Flash Point: 136.5 °C
• Appearance: /
• Density: 1.012 g/cm³
• CAS DataBase Reference: 3,5-di-tert-butylbenzene-1,2-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-di-tert-butylbenzene-1,2-diol(881376-69-8)
• EPA Substance Registry System: 3,5-di-tert-butylbenzene-1,2-diol(881376-69-8)

Safety Data

• Hazardous Substances Data: 881376-69-8(Hazardous Substances Data)

Upstream product

• 3383-21-9 3,5-di-tert-butyl-o-benzoquinone 
• 507-20-0 tertiary butyl chloride 
• 120-80-9 benzene-1,2-diol 
• 75-65-0 tert-butyl alcohol 
• 123-75-1 pyrrolidine 
• 21851-28-5 4,6-di-tert-butyl-1,2-diacetoxybenzene 
• 1665-87-8 2,4,6-tri-t-butyl-4-nitrocyclohexa-2,5-dien-1-one 
• 96-76-4 2,4-di-tert-Butylphenol 
• 4026-05-5 3-tert-butylbenzene-1,2-diol 
• 98-29-3 4-tert-Butylcatechol 
• 15512-06-8 3,6-di-tert-butylbenzene-1,2-diol 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 507-19-7 t-butyl bromide 
• 115-11-7 isobutene 

Downstream Products

• 67902-01-6 4,6-di-tert-butyl-2-phenylbenzo[d][1,3,2]dioxaborole 
• 65659-42-9 {2,4-Di-tert-butyl-6-[2-(3,5-di-tert-butyl-2-hydroxy-phenoxy)-ethoxy]-phenoxy}-acetic acid ethyl ester 
• 65659-40-7 (3,5-Di-tert-butyl-2-hydroxy-phenoxy)-acetic acid ethyl ester 
• 62785-53-9 4,6-di-tert-butyl-2,2,2-triphenyl-2λ⁵-benzo[1,3,2]dioxaphosphole 
• 108201-68-9 2-picryloxy-3,5-di-tert-butyl phenol 
• 108201-69-0 2-picryloxy-4,6-di-tert-butyl phenol 
• 85693-00-1 3,5-di-tert-butylcatechol radical 
• 22802-86-4 2,4-di-tert-butyl muconolactone 
• 15512-06-8 3,6-di-tert-butylbenzene-1,2-diol 
• 15515-54-5 2-methoxy-4,6-di-tert-butylphenol 
• 22385-74-6 3,5-Di-tert-butyl-1,2-dimethoxybenzene 
• 34896-15-6 3,5-di-tert-butyl-2-methoxyphenol 

Relevant articles and documents

Metal-free reduction of unsaturated carbonyls, quinones, and pyridinium salts with tetrahydroxydiboron/water

A series of unsaturated carbonyls, quinones, and pyridinium salts have been effectively reduced to the corresponding saturated carbonyls, dihydroxybenzenes, and hydropyridines in moderate to high yields with tetrahydroxydiboron/water as a mild, convenient, and metal-free reduction system. Deuterium-labeling experiments have revealed this protocol to be an exclusive transfer hydrogenation process from water. This journal is

Electron transfer in complexes of BII cations with organic π-acceptors: A combined experimental and quantum-chemical study

Due to their combined Lewis acidity and electron-donor capability, BII cations exhibit an interesting reactivity, which is almost unexplored so far. In this work, we compare the reduction in a dicationic diborane of a series of vicinal diones with different redox potentials, namely 3,5-di-tert-butylbenzoquinone, 3,4,5,6-tetrachlorobenzoquinone, 1,2-naphthalene-dione, 9,10-phenanthrene-dione, 2,2′-dichlorobenzil, benzil and 1,2-acenaphthylene-dione. The experimental work is complemented by quantum-chemical calculations, illuminating the electron-transfer step in the reactions.

Finding a new pathway for acid-induced nitrite reduction reaction: Formation of nitric oxide with hydrogen peroxide

Here, we report a new pathway for nitrite reduction chemistry, formation of cobalt-nitrosyl ({CoII-NO}8) with H2O2 in the reaction of a CoII-nitrito complex with a one-fold acid (H+) via the formation of a CoII-nitrous acid intermediate ({CoII-ONOH}). Mechanistic investigations using 15N-labeled-15NO2- revealed that the N-atom in the {CoII-NO}8 complex is derived from the nitrito ligand, and H2O2 came from the homolysis of the ON-OH moiety. Spectral evidence supporting the formation of the CoII-ONOH intermediate and the generation of H2O2 is also presented.