88261-98-7

Basic information

• Product Name: Silane, trimethyl(4-phenyl-1-butenyl)-, (E)-
• CAS NO: 88261-98-7
• Molecular Formula: C13H20Si
• Molecular Weight: 204.387
• Mol File: 88261-98-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(4-phenyl-1-butenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(4-phenyl-1-butenyl)-, (E)-(88261-98-7)
• EPA Substance Registry System: Silane, trimethyl(4-phenyl-1-butenyl)-, (E)-(88261-98-7)

Safety Data

• Hazardous Substances Data: 88261-98-7(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 2612-42-2 (dibromomethyl)trimethylsilane 
• 75-77-4 chloro-trimethyl-silane 
• 87837-53-4 4-phenyl 1-phenylsulphonyl but-1-ene 
• 1589-82-8 phenylmagnesium bromide 
• 59877-18-8 (E)-3-chloro-1-trimethylsilylprop-1-ene 
• 88261-99-8 (Z)-trimethyl(4-phenylbut-1-en-1-yl)silane 
• 2344-80-1 Chloromethyltrimethylsilane 
• 29955-07-5 trimethyl(diiodomethyl)silane 
• 184370-59-0 (E)-1-iodo-4-phenyl-1-butene 
• 16029-98-4 trimethylsilyl iodide 
• 768-56-9 4-Phenylbut-1-ene 
• 16520-62-0 4-Phenyl-1-butyne 
• 40277-01-8 1-(trimethylsilyl)-4-phenyl-1-butyne 

Downstream Products

• 1207204-67-8 C₁₃H₂₂OSi 
• 27066-35-9 (E)-1,4-diphenylbut-1-ene 
• 134273-12-4 (2E)-5-phenyl-2-pentanophenone 
• 33046-41-2 (E)-6-phenyl-3-hexen-2-one 

Relevant articles and documents

Regio- and enantioselective monoborylation of alkenylsilanes catalyzed by an electron-donating chiral phosphine-Copper(I) complex

An asymmetric monoborylation of alkenylsilanes catalyzed by a copper(I) complex with the chiral bisphosphine ligand BenzP* is reported. The reaction proceeded with excellent regioselectivity and high enantioselectivity to afford the corresponding opticall

Rhodium-catalyzed acylation of vinylsilanes with acid anhydrides

A catalytic acylation of vinylsilane with acid anhydride is accomplished by the use of [RhCl(CO)2]2, in which the transmetalation between vinylsilane and rhodium(I) carbonyl complex plays a key role. The application of this acylation reaction to (1-acyloxyvinyl)silanes provides synthetic methods for α-acyloxy enones, α-diketones, and their derivatives.

One-pot transformation of RCHO to (E)-RCH=CHSiMe3 using CHI3, Mn, Me3SiCl, and a catalytic amount of CrCl2

Iodoform is reduced with manganese in the presence of Me3SiCl to give Me3SiCHI2 (1). A one-pot transformation of aldehydes to (E)-1- alkenyltrimethylsilanes is then performed with iodoform, manganese, Me2SiCl, and a catalytic amount of chromium(II) chloride in THF via in situ formation of 1.