88261-99-8

Basic information

• Product Name: Silane, trimethyl(4-phenyl-1-butenyl)-, (Z)-
• CAS NO: 88261-99-8
• Molecular Formula: C13H20Si
• Molecular Weight: 204.387
• Mol File: 88261-99-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(4-phenyl-1-butenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(4-phenyl-1-butenyl)-, (Z)-(88261-99-8)
• EPA Substance Registry System: Silane, trimethyl(4-phenyl-1-butenyl)-, (Z)-(88261-99-8)

Safety Data

• Hazardous Substances Data: 88261-99-8(Hazardous Substances Data)

Upstream product

• 16520-62-0 4-Phenyl-1-butyne 
• 104-53-0 3-phenyl-propionaldehyde 
• 2612-42-2 (dibromomethyl)trimethylsilane 
• 2344-80-1 Chloromethyltrimethylsilane 
• 75-77-4 chloro-trimethyl-silane 
• 87837-53-4 4-phenyl 1-phenylsulphonyl but-1-ene 

Downstream Products

• 1207204-67-8 C₁₃H₂₂OSi 
• 883562-61-6 2-(4-phenyl-1-trimethylsilanyl-butyl)-[1,3,2]dioxaborinane 
• 88261-98-7 (E)-trimethyl(4-phenylbut-1-en-1-yl)silane 
• 16520-62-0 4-Phenyl-1-butyne 

Relevant articles and documents

Regio- and enantioselective monoborylation of alkenylsilanes catalyzed by an electron-donating chiral phosphine-Copper(I) complex

An asymmetric monoborylation of alkenylsilanes catalyzed by a copper(I) complex with the chiral bisphosphine ligand BenzP* is reported. The reaction proceeded with excellent regioselectivity and high enantioselectivity to afford the corresponding opticall

Transformation of aldehydes into (E)-1-alkenylsilanes and (E)-1-alkenylboronic esters with a catalytic amount of a chromium salt

(Diiodomethyl)trimethylsilane (Me3SiCHI2, 1) is produced by treatment of iodoform with manganese in the presence of Me 3SiCl. Aldehydes are converted to (E)-1-trimethylsilyl-1-alkenes in a stereoselective manner with a geminal dichromium reagent generated from 1, manganese, Me3SiCl, and a catalytic amount of CrCl 3[thf]3 in THF. Similarly, (E)-1-alkenylboronic esters are prepared stereoselectively in good to excellent yields by treatment of aldehydes with a geminal dichromium reagent derived from Cl2CHB(OR) 2 [(OR)2 = OCMe2CMe2O] and LiI instead of 1.

Highly Stereoselective Synthesis of Vinylsilanes from Carbonyl Compounds

The in situ generated (chlorolithiomethyl)trimethylsilane reacts at -60 deg C to -45 deg C with different aldehydes or ketones 1 to afford, after lithation with lithium naphthalenide at -78 deg C to 20 deg C, vinylsilanes 5a-h in a stereoselective manner.