88328-13-6Relevant articles and documents
Rh(i)-catalysed imine-directed C-H functionalization: via the oxidative [3 + 2] cycloaddition of benzylamine derivatives with maleimides
Chatani, Naoto,Das, Amrita
supporting information, p. 1123 - 1126 (2022/02/03)
The Rh(i)-catalysed imine-directed oxidative [3 + 2] cycloaddition of benzylamines with maleimides is reported. A wide range of both benzylamines and maleimides is applicable to the reaction. A one-pot three component strategy using benzylamines, 2-pyridi
Aerobic C?H Hydroxylation by Copper Imine Complexes: The Clip-and-Cleave Concept – Versatility and Limits
Specht, Pascal,Petrillo, Alexander,Becker, Jonathan,Schindler, Siegfried
supporting information, p. 1961 - 1970 (2021/05/03)
The intramolecular ligand hydroxylation of a series of copper(I) imine complexes during their reaction with dioxygen had been systematically studied. The so-called clip-and-cleave concept offers a facile way to oxygenate aldehydes or ketones. A copper(I)
Direct and Stereospecific [3+2] Synthesis of Pyrrolidines from Simple Unactivated Alkenes
Otero-Fraga, Jorge,Suárez-Pantiga, Samuel,Montesinos-Magraner, Marc,Rhein, Dennis,Mendoza, Abraham
supporting information, p. 12962 - 12966 (2017/09/18)
Pyrrolidines are important heterocyclic compounds with endless applications in organic synthesis, metal catalysis, and organocatalysis. Their potential as ligands for first-row transition-metal catalysts inspired a new method to access complex poly-heterocyclic pyrrolidines in one step from available materials. This fundamental step forward is based on the discovery of an essential organoaluminum promoter that engages unactivated and electron-rich olefins in intermolecular [3+2] cycloadditions.