88381-98-0

Basic information

• Product Name: N-benzyl-1-phenylbut-3-en-1-amine(SALTDATA: FREE)
• Synonyms: N-benzyl-1-phenylbut-3-en-1-amine(SALTDATA: FREE);N-benzyl-1-phenylbut-3-en-1-amine
• CAS NO: 88381-98-0
• Molecular Formula: C₁₇H₁₉N
• Molecular Weight: 237.33946
• Mol File: 88381-98-0.mol
• Article Data: 53

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-benzyl-1-phenylbut-3-en-1-amine(SALTDATA: FREE)(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-1-phenylbut-3-en-1-amine(SALTDATA: FREE)(88381-98-0)
• EPA Substance Registry System: N-benzyl-1-phenylbut-3-en-1-amine(SALTDATA: FREE)(88381-98-0)

Safety Data

• Hazardous Substances Data: 88381-98-0(Hazardous Substances Data)

Upstream product

• 24850-33-7 allyltributylstanane 
• 780-25-6 N-benzylidene benzylamine 
• 106-95-6 allyl bromide 
• 1594-94-1 allyl dimethyl boronic acid ester 
• 58044-89-6 N,N-dibenzyl-1,1,1-trifluoromethanesulfonamide 
• 2622-05-1 allylmagnesium bromide 
• 762-72-1 allyl-trimethyl-silane 
• 27845-50-7 (E)-N-benzylidenebenzylamine 
• 1730-25-2 allylmagnesium bromide 
• 100-52-7 benzaldehyde 
• 100-46-9 benzylamine 
• 2551-83-9 allyltrimethoxysilane 
• 1746-13-0 allyl phenyl ether 
• 103-49-1 dibenzylamine 

Downstream Products

• 188302-67-2 1-Benzyl-4-bromo-2-phenyl-pyrrolidine 
• 88382-06-3 N-Benzyliden-N-(1-phenyl-3-butenyl)amin-N-oxid 
• 431982-25-1 N-benzyl-N-(1-phenylbut-3-enyl)acrylamide 
• 431982-26-2 N-benzyl-2-methyl-N-(1-phenylbut-3-enyl)acrylamide 
• 226920-68-9 tert-butyl benzyl(1-phenylbut-3-enyl)carbamate 
• 102652-39-1 2-exo,6-exo-2,6-diphenyl-7-oxa-1-azabicyclo<2.2.1>heptane 
• 102734-15-6 2-exo,6-endo-2,6-diphenyl-7-oxa-1-azabicyclo<2.2.1>heptane 
• 65042-31-1 c⁽⁴⁾-hydroxy-r⁽²⁾,c⁽⁶⁾-diphenylpiperidine 
• 107520-59-2 N-Benzyl-5,6-dihydro-6-phenyl-2(1H)-pyridinone 

Relevant articles and documents

Concurrent Formation of N-H Imines and Carbonyl Compounds by Ruthenium-Catalyzed C-C Bond Cleavage of β-Hydroxy Azides

A commercial cyclopentadienylrutenium dicarbonyl dimer ([CpRu(CO)2]2) efficiently catalyzes the formation of N-H imines and carbonyl compounds simultaneously from β-hydroxy azides via C-C bond cleavage under visible light. Density functional theory calculations for the cleavage reaction support the mechanism involving chelation of alkoxy azide species and liberation of nitrogen as the driving force. The synthetic utility of the reaction was demonstrated by a new amine synthesis promoted by chemoselective allylation of imine and synthesis of isoquinoline.

Iridium-Catalyzed Reductive Alkylations of Secondary Amides

Reported herein is the first direct, metal-catalyzed reductive functionalization of secondary amides to give functionalized amines and heterocycles. The method is shown to have exceptionally broad scope with respect to suitable nucleophiles, which cover both hard and soft C nucleophiles as well as a P nucleophile. The reaction exhibits good chemoselectivity and tolerates several sensitive functional groups.

Synthesis of Cyclic Guanidines Bearing N-Arylsulfonyl and N-Cyano Protecting Groups via Pd-Catalyzed Alkene Carboamination Reactions

Palladium-catalyzed carboamination reactions of N-allylguanidines bearing cleavable N-cyano or N-arylsulfonyl protecting groups are described. The reactions afford cyclic guanidine products in good yield, and transformations of substrates bearing internal alkenes proceed with high diastereoselectivity. Deuterium labeling studies indicate these transformations proceed via anti-aminopalladation pathways.