107520-59-2

Basic information

• Product Name: 2(1H)-Pyridinone, 5,6-dihydro-6-phenyl-1-(phenylmethyl)-
• CAS NO: 107520-59-2
• Molecular Formula: C18H17NO
• Molecular Weight: 263.339
• Mol File: 107520-59-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 2(1H)-Pyridinone, 5,6-dihydro-6-phenyl-1-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(1H)-Pyridinone, 5,6-dihydro-6-phenyl-1-(phenylmethyl)-(107520-59-2)
• EPA Substance Registry System: 2(1H)-Pyridinone, 5,6-dihydro-6-phenyl-1-(phenylmethyl)-(107520-59-2)

Safety Data

• Hazardous Substances Data: 107520-59-2(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 100-52-7 benzaldehyde 
• 780-25-6 N-benzylidene benzylamine 
• 67-66-3 chloroform 
• 88381-98-0 N-(1-phenyl-3-butenyl)benzylamine 
• 100-39-0 benzyl bromide 
• 42856-43-9 1-benzylpiperidine-2,6-dione 
• 41267-62-3 1-benzyl-6-phenyl-3,4-dihydropyridin-2(1H)-one 
• 1121-89-7 piperidine-2,6-dione 
• 933803-10-2 1-benzyl-6-phenylpiperidin-2-one 
• 431982-25-1 N-benzyl-N-(1-phenylbut-3-enyl)acrylamide 
• 85390-58-5 but-3-enoic acid benzylamide 
• 85636-50-6 1-(trimethylsiloxy)-1-methoxy-1,3-butadiene 

Downstream Products

• 191087-75-9 1-Benzyl-6-phenyl-5,6-dihydro-1H-pyridine-2-thione 
• 191087-88-4 1-Benzyl-6-phenyl-3,6-dihydro-1H-pyridine-2-thione 

Relevant articles and documents

Dimethylzinc-Mediated Chlorolactamization of Homoallylic Amines with Chloroform

A novel chlorolactamization reaction of homoallylic amines has been developed. The treatment of homoallylic amines with dimethylzinc in chloroform led to the formation of the corresponding β-chlorolactams via the Prins-type cyclization of a carbamoyl chlo

Synthesis of conjugated δ-lactams using ring-closing metathesis

Addition of allyl magnesium or metallyl magnesium bromide to the N-benzyl imines of benzaldehyde and cyclohexanone, followed by acylation with acryloyl or metacryloyl chloride provided the corresponding α,β-unsaturated amides. Ring-closing metathesis of the latter with ruthenium catalyst PhCH=RuCl2(PPh3)2 in the presence of Ti(OiPr)4 provided excellent yields of the corresponding conjugated δ-lactams with both disubstituted and trisubstituted C=C bonds. Some specific trisubstitution patterns, however, as well as tetrasubstituted C=C bonds, were not obtained. In these cases, even the use of a second generation, imidazolylidene-substituted ruthenium catalyst at high temperature did not lead to success.

Stereocontrolled Syntheses of Substituted Unsaturated δ-Lactams from 3-Alkenamides

δ-Lactams have been synthesized with excellent stereocontrol of substituents by condensing 3-alkenamides with aryl aldehydes in polyphosphoric ester.