889893-53-2

Basic information

• Product Name: (S)-(-)-(4-(tert-butyldimethylsilyloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl)methanol
• Synonyms: (S)-(-)-(4-(tert-butyldimethylsilyloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl)methanol
• CAS NO: 889893-53-2
• Molecular Weight: 321.492
• Mol File: 889893-53-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-(-)-(4-(tert-butyldimethylsilyloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-(4-(tert-butyldimethylsilyloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl)methanol(889893-53-2)
• EPA Substance Registry System: (S)-(-)-(4-(tert-butyldimethylsilyloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl)methanol(889893-53-2)

Safety Data

• Hazardous Substances Data: 889893-53-2(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 62203-32-1 2-phenyl-4(bis-hydroxymethyl)-Δ²-oxazoline 
• 889893-47-4 (R)-4-hydroxymethyl-2-phenyl-4,5-dihydrooxazol-4-ylmethyl acetate 

Downstream Products

• 889893-54-3 ethyl (S,E)-3-[4-(tert-butyldimethylsiloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl]acrylate 
• 889893-55-4 ethyl (S)-3-[4-(tert-butyldimethylsiloxymethyl)-2-phenyl-4,5-dihydrooxazol-4-yl]-propionate 
• 889893-56-5 methyl (S)-4-(2-ethoxycarbonylethyl)-2-phenyl-4,5-dihydrooxazole-4-carboxylate 
• 889893-58-7 ethyl (R)-3-(4-hydroxymethyl-2-phenyl-4,5-dihydrooxazol-4-yl)propionate 
• 889893-57-6 methyl (S)-2-benzoyloxymethyl-5-oxopyrrolidine-2-carboxylate 

Relevant articles and documents

Copper-Catalyzed Enantioselective Synthesis of Oxazolines from Aminotriols via Asymmetric Desymmetrization

A copper-catalyzed enantioselective transformation of tris(hydroxymethyl)aminomethane-derived aminotriols was developed to provide multisubstituted oxazolines with a tetrasubstituted carbon center. The present transformation consisted of sequential reacti