896-33-3Relevant articles and documents
Long sought synthesis of quaternary phosphonium salts from phosphine oxides: Inverse reactivity approach
Vetter, Anna C.,Nikitin, Kirill,Gilheany, Declan G.
, p. 5843 - 5846 (2018/06/13)
Quaternary phosphonium salts (QPS), a key class of organophosphorus compounds, have previously only been available by routes involving nucleophilic phosphorus. We report the realisation of the opposite approach to QPS utilising phosphine oxides as the electrophilic partner and Grignard reagents as nucleophiles. The process is enabled through the crucial intermediacy of the derived halophosphonium salts. The route does not suffer from the slow kinetics and limited availability of many parent phosphines and a broad range of QPS were prepared in excellent yields.
One alkyl triphenyl substituted group based phosphonium salt preparation method and application
-
Paragraph 0033-0040, (2017/09/12)
The invention discloses a one alkyl triphenyl substituted group based phosphonium salt preparation method and application. The preparation method includes that a one alkyl triphenyl phosphonium salt halide I is obtained through reaction of several alkyl h
Reactions with Phosphine Alkylenes, XLII. A Sequence for the Preparation of Acetylenes Starting from Carboxylic Chlorides and Phosphorus Ylides via 1,2-Diketones.
Bestmann, Hans Juergen,Kumar, Kamlesh,Kisielowski, Lothar
, p. 2378 - 2382 (2007/10/02)
Phosphorus ylides 1 and carboxylic chlorides 2 react with transylidation to give acyl ylides 3 which are oxidized with the adduct of ozone to triphenyl phosphite to yield 1,2-diketones 5.These are converted into the bis(hydrazones) 6 which are oxidized with O2/CuCl in pyridine giving acetylenes 7.
