897440-10-7Relevant articles and documents
Synthesis and Molecular Structure of Pseudo-Hexacoordinated Pnictines Bearing 2-Phenylpyridine Ligands
Aoyagi, Shinobu,Fujita, Wataru,Ooizumi, Akihisa,Sakabe, Masato,Sato, Soichi
, p. 4373 - 4379 (2020/10/27)
The pseudo-hexacoordinated organo-pnictogen(III) compounds tris[2-(2-pyridyl)phenyl]stibine [(ppy)3Sb, 1] and tris[2-(2-pyridyl)phenyl]bismuthine [(ppy)3Bi, 2], which bear three 2-phenylpyridine (ppy) ligands, were prepared and isola
Phenanthridine Derivatives and organic light-emitting diode including the same
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, (2019/11/23)
PURPOSE: A phenanthridine derivative compound is provided to obatin an organic light emitting diode with excellent light emitting property. CONSTITUTION: A phenanthridine derivative compound is denoted by chemical formula 1 or 2. An organic light emitting diode contains an anode, a cathode, and the phenanthridine derivative compounds inserted between the anode and cathode. The organic light emitting diode further contains a hole injection layer, a hole transport layer, an electron blocking layer, a hole blocking layer, an electron transport layer, or an electron injection layer formed by monomer deposition or solution process.
Vicinal Difunctionalization of Alkenes under Iodine(III) Catalysis involving Lewis Base Adducts
Aertker, Kristina,Rama, Raquel J.,Opalach, Julita,Mu?iz, Kilian
supporting information, p. 1290 - 1294 (2017/04/18)
The influence of a 2-pyridinyl substituent on the catalytic performance of aryl iodides as catalyst in iodine(III) chemistry was explored. An efficient Lewis base adduct between the pyridine nitrogen and the electrophilic iodine(III) center was identified and confirmed by X-ray analysis. This arrangement was shown to generate a kinetically competent superior catalyst structure for the catalytic dioxygenation of alkenes. It introduces the concept of Lewis base adduct formation as a kinetic factor in iodine(I/III) catalysis. (Figure presented.).
