902745-30-6

Basic information

• Product Name: Propanedioic acid, [[4-(2-amino-2-oxoethoxy)phenyl]methylene]-
• CAS NO: 902745-30-6
• Molecular Formula: C12H11NO6
• Molecular Weight: 265.222
• Mol File: 902745-30-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, [[4-(2-amino-2-oxoethoxy)phenyl]methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, [[4-(2-amino-2-oxoethoxy)phenyl]methylene]-(902745-30-6)
• EPA Substance Registry System: Propanedioic acid, [[4-(2-amino-2-oxoethoxy)phenyl]methylene]-(902745-30-6)

Safety Data

• Hazardous Substances Data: 902745-30-6(Hazardous Substances Data)

Upstream product

• 123-08-0 4-hydroxy-benzaldehyde 
• 141-82-2 malonic acid 
• 135857-20-4 2-(4-formyl-phenoxy)-acetamide 

Downstream Products

• 873811-55-3 3-(4-carbamoylmethoxy-phenyl)-acrylic acid 

Relevant articles and documents

Competitive formation of β-amino acids, propenoic, and ylidenemalonic acids by the Rodionov reaction from malonic acid, aldehydes, and ammonium acetate in alcoholic medium

The Rodionov reaction of 49 available aliphatic and aromatic aldehydes with malonic acid and ammonium acetate in alcoholic medium, resulting in formation of β-amino acids, propenoic, and ylidenemalonic acids, was studied. Certain regioselectivity regularities of the reaction were revealed. Among the variety of ketones studied, cyclohexanone is the only whose reaction yields a β-amino acid. Unusual dehydrofluorination of 6-chloro-2-fluorocinnamic acid under the Rodionov reaction was discovered. 2005 Pleiades Publishing, Inc.