90490-46-3

Basic information

• Product Name: Acetamide, 2-bromo-N-[4-bromo-2-(tribromomethyl)phenyl]-N-methyl-
• CAS NO: 90490-46-3
• Molecular Formula: C10H8Br5NO
• Molecular Weight: 557.7
• Mol File: 90490-46-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetamide, 2-bromo-N-[4-bromo-2-(tribromomethyl)phenyl]-N-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetamide, 2-bromo-N-[4-bromo-2-(tribromomethyl)phenyl]-N-methyl-(90490-46-3)
• EPA Substance Registry System: Acetamide, 2-bromo-N-[4-bromo-2-(tribromomethyl)phenyl]-N-methyl-(90490-46-3)

Safety Data

• Hazardous Substances Data: 90490-46-3(Hazardous Substances Data)

Upstream product

• 120-66-1 N-(2-methylphenyl)acetamide 
• 573-26-2 N-methyl-N-(2-methylphenyl)acetamide 

Relevant articles and documents

Organphosphorus Compounds. XVIII. Synthesisi of 2-Phenyl-2,3-dihydro-1H-1,2-benzazaphosphole 2-Sulfide by Pyrolysis of (2-Aminobenzyl)phenyldithiophosphonic Acid

Reaction of 2-phthalimidobenzyl bromide (12b) with the dialkyl phenylphosphonites (13a-c) afforded the corresponding alkyl phosphinates (14a-c) which upon hydrazinolysis yielded the respective (2-aminobenzyl)phenylphosphinates (16a-c).Reduction of the phosphinates (16a) or (16b) with lithium aluminium hydride gave (2-aminobenzyl)phenylphosphine (15), characterized by its conversion into crystalline 2,3-diphenyl-1,2,3,4-tetrahydro-1,3-benzazaphosphorine (18). (2-Aminobenzyl)phenylphosphine (15) was heated with sulfur in benzene under reflux for 30 min to give 80percent of (2-aminobenzyl)phenyldithiophosphinic acid (20) which when heated between 100-200 deg in vacuum underwent elimination of hydrogen sulfide to yield 2-phenyl-2,3-dihydro-1H-1,2-benzazaphosphole 2-sulfide (22a).Several other new phosphorus compounds are described.An attempt to prepare a 1H-1,2-benzazaphosphole derivative by photolysis of methyl benzylphosphonic azide (7) was unsuccessful.