908013-49-0

Basic information

• Product Name: (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene
• Synonyms: (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene
• CAS NO: 908013-49-0
• Molecular Weight: 428.576
• Mol File: 908013-49-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene(908013-49-0)
• EPA Substance Registry System: (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene(908013-49-0)

Safety Data

• Hazardous Substances Data: 908013-49-0(Hazardous Substances Data)

Upstream product

• 816444-61-8 N-[(1S)-amino(4-tolyl)oxido-λ⁴-sulfanylidene]tosylamide 
• 100-41-4 ethylbenzene 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 108875-13-4 N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl chloride 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 94892-50-9 (rac)-(-)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide 
• 622-98-0 4-chloro(ethylbenzene) 
• 1861-01-4 ethylbenzene-1,1-d2 
• 459-47-2 1-ethyl-4-fluorobenzene 
• 1585-07-5 1-bromo-4-ethylbenzene 
• 100-12-9 4-ethylnitrobenzene 
• 622-96-8 4-methylethylbenzene 
• 1515-95-3 p-ethylanisole 

Relevant articles and documents

Asymmetric Synthesis of amines through rhodium-catalyzed C-H amination with sulfonimidoylnitrenes

An efficient asymmetric C-H amination of benzylic and allylic substrates, as well as of adamantane derivatives, through catalytic C-H insertion of a chiral nitrene is reported. The reaction involves a chiral rhodium(II) complex, an iodine(III) oxidant, an

Stereoselective rhodium-catalyzed lmination of sulfides

(Chemical Equation Presented) The preparation of optically active sulfilimines via the catalytic diastereoselective imination of sulfides using a chiral nitrene is described. Excellent yields up to 97% and good diastereoselectivities up to 96% have been obtained. Oxidation of the sulfilimines then stereospecifically affords the corresponding sulfoximines with very good yields in the 88-96% range.

Efficient diastereoselective intermolecular rhodium-catalyzed C-H amination

(Chemical Equation Presented) Successful matchmaking: The combination of a chiral nitrene precursor with a chiral rhodium(II) catalyst is the key factor that allows efficient intermolecular regioselective C-H amination. Good-to-excellent yields and excellent diastereoselectivities can be obtained with a stoichiometric amount of the C-H bond containing substrate. nttl = N-1,8-naphthoyl-tert-leucine.