94892-50-9

Basic information

• Product Name: (rac)-(-)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide
• Synonyms: (rac)-(-)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide
• CAS NO: 94892-50-9
• Molecular Weight: 324.425
• Mol File: 94892-50-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (rac)-(-)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide(CAS DataBase Reference)
• NIST Chemistry Reference: (rac)-(-)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide(94892-50-9)
• EPA Substance Registry System: (rac)-(-)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide(94892-50-9)

Safety Data

• Hazardous Substances Data: 94892-50-9(Hazardous Substances Data)

Upstream product

• 108875-13-4 N-(4-methylbenzenesulfonyl) 4-methylphenyl sulfonimidoyl chloride 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 3695-00-9 di(4-tosyl)amine 

Downstream Products

• 816444-62-9 (+)-(R)-N-(p-toluenesulfonyl)-p-toluenesulfonimidamide 
• 908013-49-0 (1R)-[N-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-1-aminoethylbenzene 
• 816444-61-8 N-[(1S)-amino(4-tolyl)oxido-λ⁴-sulfanylidene]tosylamide 

Relevant articles and documents

A convenient synthetic route to sulfonimidamides from sulfonamides

Sulfonimidamides were prepared in a one-pot transformation from sulfonamides, through nucleophilic substitution of sulfonimidoyl chlorides formed in situ with different amines. This methodology represents a convenient, safe, and easily accessible synthetic route to sulfonimidamides.

Sulfonimidamides: Efficient chiral iminoiodane precursors for diastereoselective copper-catalyzed aziridination of olefins

(Chemical equation presented) N-(p-Toluenesulfonyl)-p- toluenesulfonimidamide reacts with iodosylbenzene to afford in situ a chiral iminoiodane. The latter gives, in the presence of a copper(I) catalyst, a nitrene that is very efficiently transferred unde