909280-05-3

Basic information

• Product Name: (16-bromohexadecyloxy)-t-butyl-dimethyl-silane
• Synonyms: (16-bromohexadecyloxy)-t-butyl-dimethyl-silane
• CAS NO: 909280-05-3
• Molecular Weight: 435.604
• Mol File: 909280-05-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (16-bromohexadecyloxy)-t-butyl-dimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: (16-bromohexadecyloxy)-t-butyl-dimethyl-silane(909280-05-3)
• EPA Substance Registry System: (16-bromohexadecyloxy)-t-butyl-dimethyl-silane(909280-05-3)

Safety Data

• Hazardous Substances Data: 909280-05-3(Hazardous Substances Data)

Upstream product

• 59101-28-9 16-bromohexadecan-1-ol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 907218-93-3 16-(2,5-dimethoxyphenylamino)hexadecan-1-ol 
• 907218-97-7 [16-(t-butyldimethylsilanyloxy)hexadecyl]-(2,5-dimethoxyphenyl)amine 

Relevant articles and documents

O -phenylene octamers as surface modifiers for homeotropic columnar ordering of discotic liquid crystals

Large-area homeotropic columnar ordering of π-conjugated discotic liquid crystals (LCs) is crucial for certain device applications but generally hard to achieve. Here we report polymeric o-phenylene octamer poly-1 and its monomer 1 as the first surface modifiers for homeotropic columnar order of a variety of discotic LCs up to a macroscopic length scale. Their octameric o-phenylene parts are known to fold helically into a cylinder that is reminiscent of a π-stacked column of discotic LCs. Through-view X-ray diffraction patterns of 1 suggested that this molecule adheres to the glass substrate and directs its cylindrical axis perpendicular to the glass surface. This "face-on" orientation likely nucleates the homeotropic columnar order of discotic LC materials.

Solid-phase synthesis of quinol fatty alcohols, design of N/O-substituted quinol fatty alcohols and comparative activities on axonal growth

Following the promising activity of Q2FA15 on axonal growth, two new series of N/O-substituted QFAs were synthesized, based on a SN2-type reaction. O-alkylated QFA bearing 14 carbon atoms on the side chain (n = 14) shows a very potent activity on axonal growth though lowered when compared to Q2FA15. While O-alkylation allows good retention of the biological activity, N-alkylation abolishes it nonetheless. A solid-phase-supported synthesis of Q2FA15 allowing the conception of new hybrid compounds is also described.