91222-27-4Relevant articles and documents
A general and mild Cu-catalytic: N -arylation of iminodibenzyls and iminostilbenes using unactivated aryl halides
Yao, Wubing,Zhang, Bin,Li, Rongrong,Jiang, Huajiang,Chen, Xiaoying,Li, Fang
, p. 49600 - 49604 (2017)
A ligand-free, highly efficient Cu-catalytic N-arylation of iminodibenzyl and iminostilbene derivatives with a broad scope of unactivated aryl halides under mild conditions has been developed for the first time. Moreover, the first Ni-based catalytic syst
PIFA-Promoted, Solvent-Controlled Selective Functionalization of C(sp2)-H or C(sp3)-H: Nitration via C-N Bond Cleavage of CH3NO2, Cyanation, or Oxygenation in Water
Mudithanapelli, Chandrashekar,Dhorma, Lama Prema,Kim, Mi-Hyun
supporting information, (2019/05/07)
A novel nitration (via C(sp3)-N breaking/C(sp2)-N formation with CH3NO2) mediated by [bis(trifluoroacetoxy)iodo]benzene (PIFA) is described. The NO2 transfer from CH3NO2 to the aromatic group of the substrate is possible with careful selection of the solvent, NaX, and oxidant. In addition, the solvent-controlled C(sp2)-H functionalization can shift to an α-C(sp3)-H functionalization (cyanation or oxygenation) of the α-C(sp3)-H of cyclic amines.
Novel method for nickel-catalyzed imino dibenzyl derivative amination
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Paragraph 0047-0050, (2018/04/01)
The invention relates to a novel method which can smoothly catalyze an organic light emitting diodes (OLEDs) material unit - imino dibenzyl derivative to undergo amination with iodo- or bromo- arene under mild conditions by using a cheap and easily-obtain
