91544-03-5Relevant articles and documents
Synthesis, photophysical and electrophosphorescent properties of fluorene-based platinum(II) complexes
Yuen, Mai-Yan,Kui, Steven C. F.,Low, Kam-Hung,Kwok, Chi-Chung,Chui, Stephen Sin-Yin,Ma, Chun-Wah,Zhu, Nianyong,Che, Chi-Ming
supporting information; experimental part, p. 14131 - 14141 (2011/02/23)
A series of platinum(II) complexes bearing tridentate cyclometalated C^N^N (C^N^N=6-phenyl-2,2'-bipyridine and π-extended R-C^N^N=3-[6'-(naphthalen-2''- yl)pyridin-2'-yl]isoquinoline) ligands with fluorene units have been synthesised and their photophysic
Homochiral isoquinolines by lipase-catalysed resolution and their diastereoselective functionalisation
Guanti, Giuseppe,Riva, Renata
, p. 1185 - 1200 (2007/10/03)
Kinetic resolution of racemic isoquinoline alcohols and acetates has been successfully accomplished using lipases as chiral catalysts. The diastereoselective functionalisation of the isoquinoline moiety through the addition of C-nucleophiles to O-protected alcohol 9a in the presence of phenyl chloroformate has been carried out and dihydroquinolyl alcohol derivatives with high diastereomeric excess have been prepared.
Electrophilic activation of acetyl-substituted heteroaromatic compounds
Klumpp,Garza,Sanchez Jr.,Lau,De Leon
, p. 8997 - 9000 (2007/10/03)
The chemistry of acetyl-substituted pyridines, thiazoles, quinoline, isoquinolines, and pyrazine (1-9 and 28) has been studied. These heteroarenes (1-8) condense with benzene in good yields (74-96%) in the Bronsted superacid, CF3SO3H (triflic acid). In these acid-catalyzed hydroxyalkylation reactions, compounds 1-8 are significantly more reactive than acetophenone. It is proposed that compounds 1-8 readily form dicationic electrophiles in triflic acid.
