915769-12-9

Basic information

• Product Name: 1-[(E)-but-1-en-3-ynyl]-2,6,6-trimethylcyclohexa-1,3-diene
• Synonyms: 1-[(E)-but-1-en-3-ynyl]-2,6,6-trimethylcyclohexa-1,3-diene
• CAS NO: 915769-12-9
• Molecular Weight: 172.27
• Mol File: 915769-12-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-[(E)-but-1-en-3-ynyl]-2,6,6-trimethylcyclohexa-1,3-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[(E)-but-1-en-3-ynyl]-2,6,6-trimethylcyclohexa-1,3-diene(915769-12-9)
• EPA Substance Registry System: 1-[(E)-but-1-en-3-ynyl]-2,6,6-trimethylcyclohexa-1,3-diene(915769-12-9)

Safety Data

• Hazardous Substances Data: 915769-12-9(Hazardous Substances Data)

Upstream product

• 915769-15-2 1-[(E)-4-(trimethylsilyl)but-1-en-3-ynyl]-2,6,6-trimethylcyclohexa-1,3-diene 
• 116-26-7 safranal 

Relevant articles and documents

Stereoselective synthesis of trienoic acids: Synthesis of retinoic acids and analogues

Stereoselective construction of conjugated trienoic acids was achieved through two successive Stille reactions, the first step consisting of the coupling of (E)-1,2-bis(tributylstannyl)ethene and tributylstannyl (Z)- or (E)-3-iodoalk-2-enoates. Two different routes were used for the second step: (1) cross-coupling of the stannyldienoic acid reagents and vinyl iodides, or (2) cross-coupling of vinylstannane reagents and the tributylstannyl 5-iodopenta-2,4-dienoates generated by iododestannylation of stannyldienes. Vinylstannanes synthesized by stannylmetalation of the Negishi dienyne derived from β- or α-ionone and safranal thus provided access to stereodefined retinoic acids. Some retinoid and yne analogues were also prepared by Sonogashira coupling. Georg Thieme Verlag Stuttgart.