916069-02-8

Basic information

• Product Name: 4H-1-Benzopyran-4-one, 3-[[(2S,6S)-5,6-dihydro-6-methyl-5-oxo-2H-pyran-2-yl]oxy]-5,7-bis(phen ylmethoxy)-2-[4-(phenylmethoxy)phenyl]-
• CAS NO: 916069-02-8
• Molecular Formula: C42H34O8
• Molecular Weight: 666.727
• Mol File: 916069-02-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4H-1-Benzopyran-4-one, 3-[[(2S,6S)-5,6-dihydro-6-methyl-5-oxo-2H-pyran-2-yl]oxy]-5,7-bis(phen ylmethoxy)-2-[4-(phenylmethoxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 4H-1-Benzopyran-4-one, 3-[[(2S,6S)-5,6-dihydro-6-methyl-5-oxo-2H-pyran-2-yl]oxy]-5,7-bis(phen ylmethoxy)-2-[4-(phenylmethoxy)phenyl]-(916069-02-8)
• EPA Substance Registry System: 4H-1-Benzopyran-4-one, 3-[[(2S,6S)-5,6-dihydro-6-methyl-5-oxo-2H-pyran-2-yl]oxy]-5,7-bis(phen ylmethoxy)-2-[4-(phenylmethoxy)phenyl]-(916069-02-8)

Safety Data

• Hazardous Substances Data: 916069-02-8(Hazardous Substances Data)

Upstream product

• 88607-79-8 (E)-1-(2,4-bis(benzyloxy)-6-hydroxyphenyl)-3-(4-(benzyloxy)phenyl)prop-2-en-1-one 
• 100-39-0 benzyl bromide 
• 4208-64-4 (S)-1-(2-furanyl)ethanol 
• 247244-65-1 L-aculose 
• 480-41-1 5,7-Dihydroxy-2-(4-hydroxy-phenyl)-chroman-4-on 
• 96333-59-4 5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4H-chromen-4-one 
• 1192-62-7 1-(2-furyl)-1-ethanone 
• 865484-73-7 tert-butyl ((2S,6S)-6-methyl-5-oxo-5,6-dihydro-2H-pyran-2-yl) carbonate 
• 23405-70-1 5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-3-hydroxy-4H-chromen-4-one 

Downstream Products

• 133882-73-2 Kaempferol-3-O-(2,4-di-O-acetyl-alpha-L-rhamnopyranoside) 
• 77307-50-7 Kaempferol-3-O-(3,4-O-diacetyl-α-L-rhamnopyranoside) 
• 135618-17-6 Kaempferol-3-O-(4-O-acetyl-alpha-L-rhamnopyranoside) 
• 482-39-3 kaempferol 3-rhamnoside 
• 916069-08-4 (2S,3S,4S,5R,6S)-6-((5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4-oxo-4H-chromen-3- yl)oxy)-5-hydroxy-2-methyltetrahydro-2H-pyran-3,4-diyl diacetate 
• 916069-07-3 (2S,3R,4R,5R,6S)-2-((5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4-oxo-4H-chromen-3-yl)oxy)-4-hydroxy-6-methyltetrahydro-2H-pyran-3,5-diyl diacetate 
• 916069-06-2 (2S,3R,4S,5R,6S)-6-((5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4-oxo-4H-chromen-3-yl)oxy)-4,5-dihydroxy-2-methyltetrahydro-2H-pyran-3-yl acetate 
• 916069-04-0 5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-3-(((2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyltetrahydro-2H-pyran-2-yl)oxy)-4H-chromen-4-one 
• 916069-05-1 6-(5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4-oxo-4H-chromen-3-yloxy)-3,6-dihydro-2-methyl-2H-pyran-3-yl acetate 
• 910041-19-9 (2S,3R,4R,5S,6S)-2-((5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4-oxo-4H-chromen-3-yl)oxy)-6-methyltetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 735315-15-8 Kaempferol-3-O-(2,3,4-tri-O-acetyl-alpha-L-rhamnopyranoside) 
• 916069-03-9 3-((2S,5R,6S)-5,6-dihydro-5-hydroxy-6-methyl-2H-pyran-2-yloxy)-5,7-bis(benzyloxy)-2-(4-(benzyloxy)phenyl)-4H-chromen-4-one 

Relevant articles and documents

De novo asymmetric syntheses of SL0101 and its analogues via a palladium-catalyzed glycosylation

(Chemical Equation Presented) The enantioselective syntheses of naturally occurring kaempferol glycoside SL0101 (1a) and its analogues 1b-e, as well as their enantiomers, have been achieved in 7-10 steps. The routes rely upon a diastereoselective palladium-catalyzed glycosylation, ketone reduction, and dihydroxylation to introduce the rhamno-stereochemistry. The asymmetry of the sugar moiety of these kaempferol glycosides was derived from Noyori reduction of an acylfuran. An acetyl group shift from an axial (C-2) to equatorial position (C-3) under basic conditions was also described.