917507-05-2Relevant articles and documents
Copper-Catalyzed Alkenylation of Alcohols with β-Nitrostyrenes via a Radical Addition-Elimination Process
Guo, Sheng-Rong,Yuan, Yan-Qin
supporting information, p. 1961 - 1968 (2015/09/01)
A new method for the preparation of allylic alcohol derivatives has been developed via a radical mechanism using DTBP as the radical initiator promoted by copper salt. The C(sp3)-H bond in various alcohols, toluene derivatives, and alkanes were successfully converted into C-C bonds to yield the desired products in moderate to good yields.
Vinyl hydrogen more reactive than benzyl hydrogen toward base in significantly twisted styrenes
Mori, Hajime,Matsuo, Takafumi,Yoshioka, Yasunori,Katsumura, Shigeo
, p. 3093 - 3095 (2007/10/03)
The novel example of vinyl hydrogen more reactive than benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D2O quenching. The characteristic nature of the vinyl hydrogen, which is activated by