917810-87-8Relevant articles and documents
Pd-catalyzed asymmetric allylic alkylation with nitromethane using a chiral diaminophosphine oxide: (S,RP)-Ph-DIAPHOX. Enantioselective synthesis of (R)-preclamol and (R)-baclofen
Nemoto, Tetsuhiro,Jin, Long,Nakamura, Hiroshi,Hamada, Yasumasa
, p. 6577 - 6581 (2007/10/03)
A Pd-catalyzed asymmetric allylic alkylation with nitromethane using an aspartic acid-derived P-chirogenic diaminophosphine oxide [(S,RP)-Ph-DIAPHOX] is described. This method was successfully applied to enantioselective synthesis of (R)-precla