92683-58-4Relevant articles and documents
Use of Radical Ring-Opening for Introduction of Alkyl and Substituted Alkyl Groups with Stereochemical Control: A Synthetic Application of Cyclopropylcarbinyl Radicals
Clive, Derrick L. J.,Daigneault, Sylvain
, p. 3801 - 3814 (2007/10/02)
Cyclopropylcarbinols 2a and 2b (see Scheme I), which are accessible by a number of routes, can be converted into the corresponding radicals 3a and 3b, respectively.These radicals undergo peripheral ring-opening of the cyclopropyl substructure to afford su
MODEL STUDIES ON THE SYNTHESIS OF PSEUDOMONIC ACIDS
Fleet, G.W.J.,Spensley C.R.C.
, p. 109 - 112 (2007/10/02)
The efficient synthesis of racemic 4α-acetonyl-2β,3β-dihydroxycyclohexane-1α-acetanilide (1) from cyclohex-2-enol demonstrates a potencial strategy for the control of the stereochemistry of the four contiguous chiral carbon atoms in the pyran ring of pseu