930299-14-2

Basic information

• Product Name: ethyl (S_S,2R,3S)-(+)-2-N-(diphenylmethyleneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate
• Synonyms: ethyl (S_S,2R,3S)-(+)-2-N-(diphenylmethyleneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate
• CAS NO: 930299-14-2
• Molecular Weight: 510.657
• Mol File: 930299-14-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl (S_S,2R,3S)-(+)-2-N-(diphenylmethyleneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (S_S,2R,3S)-(+)-2-N-(diphenylmethyleneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate(930299-14-2)
• EPA Substance Registry System: ethyl (S_S,2R,3S)-(+)-2-N-(diphenylmethyleneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate(930299-14-2)

Safety Data

• Hazardous Substances Data: 930299-14-2(Hazardous Substances Data)

Upstream product

• 69555-14-2 ethyl N-diphenylmethylene glycine 
• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 
• 749253-91-6 (S_S,2S,3S)-(+)-ethyl 2-N-(diphenylmethylideneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate 

Downstream Products

• 749253-93-8 (4R,5S)-(-)-ethyl 2-oxo-5-phenylimidazolidine-4-carboxylate 
• 69555-14-2 ethyl N-diphenylmethylene glycine 
• 350479-90-2 (S,E)-N-benzylidene-4-methylbenzenesulfinamide 

Relevant articles and documents

Asymmetric synthesis of anti- and syn-2,3-diamino esters using sulfinimines. Water and concentration effects

(Chemical Equation Presented) In the absence of water, an excess of the lithium enolate of N-(diphenylmethylene)glycine ethyl ester (4) adds to sulfinimines to give syn-2,3-diamino esters 6, and in the presence of water, this enolate gives the anti-2,3-diamino esters 5. These unusual results are interpreted in terms of those factors that inhibit the retro-Mannich fragmentation in the diamino esters.