93366-44-0

Basic information

• Product Name: 1,4-Dioxaspiro[4.5]dec-6-ene, 6-[(4-methoxyphenyl)sulfinyl]-, (S)-
• CAS NO: 93366-44-0
• Molecular Formula: C15H18O4S
• Molecular Weight: 294.372
• Mol File: 93366-44-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-Dioxaspiro[4.5]dec-6-ene, 6-[(4-methoxyphenyl)sulfinyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Dioxaspiro[4.5]dec-6-ene, 6-[(4-methoxyphenyl)sulfinyl]-, (S)-(93366-44-0)
• EPA Substance Registry System: 1,4-Dioxaspiro[4.5]dec-6-ene, 6-[(4-methoxyphenyl)sulfinyl]-, (S)-(93366-44-0)

Safety Data

• Hazardous Substances Data: 93366-44-0(Hazardous Substances Data)

Upstream product

• 6462-50-6 sodium 4-methoxybenzenesulfinate 
• 31401-23-7 p-methoxybenzenesulfinyl chloride 
• 70156-98-8 6-bromo-1,4-dioxaspiro[4,5]dec-6-ene 
• 1942-34-3 (S_S)-(-)-menthyl-p-methoxybenzenesulfinate 

Downstream Products

• 2916-31-6 2,2-dimethyl-1,3-dioxolane 
• 93366-40-6 (S)-(+)-2-(p-anisylsulfinyl)-2-cyclohexenone 
• 24965-87-5 (S)-3-methylcyclohexanone 
• 13368-65-5 (3R)-3-methylcyclohexanone 
• 74006-76-1 (R)-(+)-3-(1-methylethyl)cyclohexanone 
• 23396-36-3 (3S)-3-isopropylcyclohexanone 

Relevant articles and documents

ASYMMETRIC SYNTHESIS USING ENANTIOMERICALLY PURE 2-(p-ANISYLSULFINYL)-2-CYCLOALKENONES

Conjugate additions of many organometallic reagents to 2-(p-anisylsulfinyl)-2-cycloalkenones, 2, proceed with much greater diastereoselectivity than additions to the corresponding 2-(p-tolylsulfinyl)-2-cycloalkenones, 7.Complexation of 2 with zinc dibromide followed by addition of various Grignard reagents lead, after reductive removal of the sulfoxide, to 3-substituted cycloalkanones of higher optical purity than those obtained from 7.Addition of methyltitanium triisopropoxide to 2-(p-anisylsulfinyl)-2-cyclohexenone, 2b, in the absence of zinc dibromide, proceeds with virtually complete asymmetric induction.