940-58-9

Basic information

• Product Name: 4-METHOXYPHENYL CHLOROTHIOFORMATE
• Synonyms: 4-METHOXYPHENYL CHLOROTHIOFORMATE
• CAS NO: 940-58-9
• Molecular Formula: C₈H₇ClO₂S
• Molecular Weight: 202.66
• Mol File: 940-58-9.mol
• Article Data: 7

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-METHOXYPHENYL CHLOROTHIOFORMATE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXYPHENYL CHLOROTHIOFORMATE(940-58-9)
• EPA Substance Registry System: 4-METHOXYPHENYL CHLOROTHIOFORMATE(940-58-9)

Safety Data

• Hazardous Substances Data: 940-58-9(Hazardous Substances Data)

Upstream product

• 463-71-8 thiophosgene 
• 150-76-5 4-methoxy-phenol 

Downstream Products

• 26011-92-7 Thiocarbonic acid O-[5-chloro-2-(2,4-dichloro-phenoxy)-phenyl] ester O-(4-methoxy-phenyl) ester 
• 26012-07-7 Thiocarbonic acid O-[5-chloro-2-(4-chloro-3-trifluoromethyl-phenoxy)-phenyl] ester O-(4-methoxy-phenyl) ester 
• 26011-99-4 Thiocarbonic acid O-[4-bromo-5-chloro-2-(2,4-dichloro-phenoxy)-phenyl] ester O-(4-methoxy-phenyl) ester 
• 19387-45-2 O-(4-methoxy-phenyl)-thiocarbonic morpholine-4-carbothioic thioanhydride 
• 26012-03-3 Thiocarbonic acid O-[5-chloro-2-(2,4-dibromo-phenoxy)-phenyl] ester O-(4-methoxy-phenyl) ester 
• 10381-16-5 O-4-methoxyphenyl thiocarbamate 
• 91983-59-4 5-(4-methoxyphenyloxy)-1,2,3,4-thiatriazole 
• 109514-84-3 4-Methoxy-thiocarbanilsaeure-<4-methoxy-phenyl-ester> 
• 97723-35-8 3,4-Dichlor-benzyl-thiocarbamidsaeure-<4-methoxy-phenyl-ester> 
• 10577-73-8 O-(4-methoxyphenyl) N-phenylthioncarbamate 
• 109648-57-9 3-Phenyl-6-hydroxy-thiocarbanilsaeure-(4-methoxy-phenyl-ester) 
• 96651-96-6 3.4-Dichlor-thiocarbanilsaeure-<4-methoxy-phenyl-ester> 
• 130255-56-0 5-(4-Methoxy-phenoxy)-[1,2,4]dithiazol-3-ylideneamine; hydrochloride 
• 127082-48-8 2,6-Bis-(4-methoxy-phenoxy)-4λ⁴-[1,2,4]dithiazolo[1,5-b][1,2,4]dithiazole 

Relevant articles and documents

Oxidative desulfurization-fluorination reaction promoted by [bdmim][F] for the synthesis of difluorinated methyl ethers

A new ionic liquid [bdmim][F] has been prepared and fully characterized. Its potential as a fluoride source for the desulfurization-fluorination process has been evaluated with success. The carbon-sulfur double bond of xanthates and thiocarbonates has bee

Radical OfC transposition: A metal-free process for conversion of phenols into benzoates and benzamides

We report a metal-free procedure for transformation of phenols into esters and amides of benzoic acids via a new radical cascade. Diaryl thiocarbonates and thiocarbamates, available in a single high-yielding step from phenols, selectively add silyl radicals at the sulfur atom of the CdS moiety. This addition step, analogous to the first step of the Barton-McCombie reaction, produces a carbon radical which undergoes 1,2 OfC transposition through an O-neophyl rearrangement. The usually unfavorable equilibrium in the reversible rearrangement step is shifted forward via a highly exothermic C-S bond scission in the O-centered radical, which furnishes the final benzoic ester or benzamide product. The metal-free preparation of benzoic acid derivatives from phenols provides a potentially useful alternative to metal-catalyzed carbonylation of aryl triflates.

Episulfidation of strained cycloalkenes in the thermolysis of 5-aryloxy-1,2,3,4-thiatriazoles

The thermolysis of 5-aryloxythiatriazoles 1 in the presence of norbornene (2a) and trans-cyclooctene (trans-2b) affords the corresponding thiiranes 3a and trans-3b in moderate yields. First-order kinetics are observed, suggesting that a sulfur intermediate, presumably dinitrogen sulfide, is generated in the fragmentation process of 1, which then serves as the active sulfur atom donor.