941293-00-1

Basic information

• Product Name: 3-(4-tert-butoxyphenyl)propionaldehyde
• Synonyms: 3-(4-tert-butoxyphenyl)propionaldehyde
• CAS NO: 941293-00-1
• Molecular Weight: 206.285
• Mol File: 941293-00-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-(4-tert-butoxyphenyl)propionaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-tert-butoxyphenyl)propionaldehyde(941293-00-1)
• EPA Substance Registry System: 3-(4-tert-butoxyphenyl)propionaldehyde(941293-00-1)

Safety Data

• Hazardous Substances Data: 941293-00-1(Hazardous Substances Data)

Upstream product

• 132307-87-0 3-(4-tert-butoxyphenyl)-propan-1-ol 
• 5597-50-2 3-(4-hydroxyphenyl)propionic acid methyl ester 
• 155904-35-1 3-(4-tert-butoxy-phenyl)-acrylic acid 
• 21323-98-8 3-(4-tert-butoxyphenyl)-propionic acid 
• 57699-45-3 p-tert-butoxybenzaldehyde 
• 1400684-94-7 3-(4-(tert-butoxy)phenyl)-N-methoxy-N-methylpropanamide 
• 106-44-5 p-cresol 
• 15359-98-5 4-(tert-butoxy)toluene 

Downstream Products

• 941293-02-3 (S)-β-4-tert-butoxyphenyl-γ-(S)-N-benzyl-α-methylbenzylamino-propylalcohol 
• 941293-01-2 C₁₄H₂₃NO₂ 
• 941293-03-4 (s)-β-4-tert-butoxylphenyl-γ-Fmoc-amino-propylalcohol 

Relevant articles and documents

Enolesters as chain end-functionalizing agents for the living ring opening metathesis polymerization

Functional enolethers have previously been used to introduce functional end groups at the chain end of ruthenium carbene complex initiated living ring opening metathesis polymers. Here, we investigated whether the weaker π-donating enolesters could equally be used in regio selective reactions with ruthenium carbene complexes and thus as polymer end-functionalization reagents. Enolesters such as vinyl acetate, butenyl acetate, 3-(4-(tert-butoxy)phenyl)propenyl acetate and 6-(((benzyloxy)carbonyl)amino)hex-1-en-1-yl acetate were used as living ROMP terminating agents. All gave the expected end groups proving that enolesters are synthetically easily accessible targets for living ROMP end-functionalization.

Practical synthesis of enantiomerically pure β2-amino acids via proline-catalyzed diastereoselective aminomethylation of aldehydes

Proline-catalyzed diastereoselective aminomethylation of aldehydes using a chiral iminium ion, generated from a readily prepared precursor, provides α-substituted-β-amino aldehydes with 85:15 to 90: 10 dr. The α-substituted-β-amino aldehydes can be reduce