943448-07-5

Basic information

• Product Name: 5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohex-2-en-1-one
• Synonyms: 5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohex-2-en-1-one
• CAS NO: 943448-07-5
• Molecular Weight: 254.445
• Mol File: 943448-07-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohex-2-en-1-one(943448-07-5)
• EPA Substance Registry System: 5-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohex-2-en-1-one(943448-07-5)

Safety Data

• Hazardous Substances Data: 943448-07-5(Hazardous Substances Data)

Upstream product

• 33646-18-3 dimethyl 2-(3-oxocyclohexyl)malonate 
• 160701-51-9 1-(tert-Butyl-dimethyl-silanyloxy)-3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-benzene 
• 108330-00-3 (E)-4-<(tert-butyldimethylsilyl)oxy>-1-iodo-1-butene 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 38231-56-0 methyl 2-(1,4-dioxaspiro[4.5]dec-7-yl)acetate 
• 5502-11-4 30(2-hydroxyethyl)-1-cyclohexanone 
• 7076-70-2 2-(1,4-dioxaspiro[4.5]decan-7-yl)ethan-1-ol 
• 930-68-7 cyclohexenone 
• 943448-05-3 C₁₄H₂₈O₂Si 
• 861924-46-1 2-(1,4-dioxaspiro[4.5]dec-7-yl)malonic acid dimethyl ester 
• 943448-06-4 C₁₇H₃₆O₂Si₂ 

Downstream Products

• 943448-08-6 trifluoro-methanesulfonic acid 3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohexa-1,5-dienyl ester 
• 943448-09-7 4-{3-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-cyclohexa-1,5-dienyl}-butyric acid ethyl ester 

Relevant articles and documents

Regioselective Iridium-Catalyzed Asymmetric Monohydrogenation of 1,4-Dienes

A highly efficient regio- and enantioselective monohydrogenation of 1,4-dienes has been realized using an iridium catalyst with a chiral N,P-ligand under mild conditions. The substrate scope was studied and included both unfunctionalized as well as functionalized substituents on the meta- or para-position. Substrates having substituents with functionalities such as silyl protected alcohols or ketals were monohydrogenated in high regioselectivity and high enantiomeric excess (up to 98% ee).

An Approach to the Synthesis of Stenine

A type 2 N-acylnitroso intramolecular Diels-Alder reaction followed by reductive N - O bond cleavage formed the B and C rings of the Stemona alkaloid stenine. Further elaboration provided the functionalized tricyclic core.