947685-88-3

Basic information

• Product Name: (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate
• Synonyms: (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate
• CAS NO: 947685-88-3
• Molecular Weight: 390.35
• Mol File: 947685-88-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate(947685-88-3)
• EPA Substance Registry System: (1R,6S,7S)-7-formyl-2,2,6-trimethylbicyclo[4.2.0]octan-7-yl pentafluorobenzoate(947685-88-3)

Safety Data

• Hazardous Substances Data: 947685-88-3(Hazardous Substances Data)

Upstream product

• 849405-73-8 3,3-dimethylcyclohex-1-en-1-yl trifluoromethanesulfonate 
• 503-47-9 1,3,3-trimethyl-1-cyclohexene 

Relevant articles and documents

Enantioselective [2 + 2] cycloaddition of unactivated alkenes with α-acyloxyacroleins catalyzed by chiral organoammonium salts

We report the first example of an organocatalytic enantioselective [2 + 2] cycloaddition reaction of unactivated alkenes with α-acyloxyacroleins to give optically active 1-acyloxycyclobutanecarbaldehydes and subsequent ring expansion to give optically active 2-hydroxycyclopentanone derivatives. Organoammonium salt, H-L-Phe-L-Leu-N(CH2CH2)2-reduced triamine?2.6HNTf2, is a highly effective chiral catalyst for the above enantioselective [2 + 2] cycloaddition. Thus, we have developed a novel and useful formal enantioselective [2 + 3] cycloaddition through two steps. Copyright