94925-95-8Relevant articles and documents
METHOD FOR PRODUCING CYCLOLAVANDULOL AND DERIVATIVE THEREOF
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Paragraph 0074-0081, (2016/08/29)
A targeted compound is produced simply, efficiently and selectively. Specifically provided are a method for producing (2,4,4-trimethyl-2-cyclohexene)methanol, comprising the steps of: reacting the carbonyl group of 2,4,4-trimethyl-2-cyclohexenone (1) to o
Regioselectivity and Steric Course of Lewis Acid Promoted Ring Enlargement of Cyclohexadiene Complexes with Carbon Monoxide
Eilbracht, Peter,Jelitte, Ruediger,Walz, Leonhard
, p. 3473 - 3489 (2007/10/02)
Treating the tricarbonyliron complexes 5 and 7 of substituted cyclohexadienes with AlCl3 yields complexes 6, 8, and 9 of seven-membered ring ketones, containing carbon monoxide inserted into one of the double bonds with high regioselectivity depending on the substitution pattern.The mechanism of this ring enlargement is discussed, and an X-ray analysis of 8e is carried out.