95018-41-0

Basic information

• Product Name: Pyridine, 2,3,4,5-tetrahydro-6-(phenylmethyl)-
• CAS NO: 95018-41-0
• Molecular Formula: C12H15N
• Molecular Weight: 173.258
• Mol File: 95018-41-0.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: Pyridine, 2,3,4,5-tetrahydro-6-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Pyridine, 2,3,4,5-tetrahydro-6-(phenylmethyl)-(95018-41-0)
• EPA Substance Registry System: Pyridine, 2,3,4,5-tetrahydro-6-(phenylmethyl)-(95018-41-0)

Safety Data

• Hazardous Substances Data: 95018-41-0(Hazardous Substances Data)

Upstream product

• 35843-79-9 (6-chloro-1-hexyn-1-yl)benzene 
• 536-74-3 phenylacetylene 
• 522-33-8 Tripiperidin 
• 856120-87-1 (6-azidohex-1-yn-1-yl)benzene 
• 928-90-5 5-hexyl-1-ol 
• 591-50-4 iodobenzene 
• 936501-77-8 6-phenyl-5-hexyn-1-mesylate 
• 114635-58-4 C₁₈H₂₀N₂O₅S 
• 95018-22-7 [1-(6-Benzyl-3,4-dihydro-2H-pyridin-1-yl)-meth-(E)-ylidene]-tert-butyl-amine 
• 135469-76-0 6-phenylhex-5-yn-1-amine 
• 95018-15-8 tert-Butyl-[1-(2-phenylselanyl-piperidin-1-yl)-meth-(E)-ylidene]-amine 
• 89656-61-1 tert-Butyl-[1-(3,4-dihydro-2H-pyridin-1-yl)-meth-(E)-ylidene]-amine 
• 85152-52-9 N-(N'-tert-butylformimidoyl)piperidine 
• 100-39-0 benzyl bromide 

Downstream Products

• 203452-46-4 (2R)-2-benzylpiperidine 
• 99112-94-4 (2S)-2-benzylpiperidine 
• 882696-36-8 2-benzyl-1-(phenylsilyl)piperidine 
• 32838-55-4 2-benzylpiperidine 

Relevant articles and documents

A Commercially Available and User-Friendly Catalyst for Hydroamination Reactions under Technical Conditions

The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalyst was also found active in intermolecular aza-Michael reactions.

Intramolecular hydroamination of aminoalkynes with silver-phenanthroline catalysts

(Chemical Equation Presented) Intramolecular hydroamination of several aminoalkynes catalyzed by silver-phenanthroline complexes is reported. This catalyst system complements previous protocols by employing air- and moisture-stable complexes without compromising activity or reaction control. Some of the hydroamination products are subject to a useful aerobic oxidation. Silver-phenanthroline complexes have successfully demonstrated efficacy in the desymmetrization of a prochiral diyne.

Bis(phosphinimino)methanide rare earth amides: Synthesis, structure, and catalysis of hydroamination/cyclization, hydrosilylation, and sequential hydroamination/hydrosilylation

A series of yttrium and lanthanide amido complexes [Ln{N-(SiHMe 2)2}2{CH(PPh2NSiMe3) 2}] (Ln = Y, La, Sm, Ho, Lu) were synthesized by three different pathways. The title compounds can be obtained either from [Ln{N(SiHMe 2)2}3(thf)2] and [CH 2(PPh2NSiMe3)2] or from KN-(SiHMe2)2 and [Ln(CH(PPh2NSiMe 3)2}-Cl2]2, while in a third approach the lanthanum compound was synthesized in a one-pot reaction starting from K{CH(PPh2NSiMe3)2}, LaCl3, and KN-(SiHMe2)2. All the complexes have been characterized by single-crystal X-ray diffraction. The new complexes, [Ln{N(SiHMe 2)2}2{CH(PPh2NSiMe3) 2}], were used as catalysts for hydroamination/cyclization and hydrosilylation reactions. A clear dependence of the reaction rate on the ionic radius of the center metal was observed, showing the lanthanum compound to be the most active one in both reactions. Furthermore, a combination of both reactions - a sequential hydroamination/hydrosilylation reaction - was also investigated.