950510-09-5Relevant articles and documents
Ammonium bromides/KF catalyzed trifluoromethylation of carbonyl compounds with (trifluoromethyl)trimethylsilane and its application in the enantioselective trifluoromethylation reaction
Mizuta, Satoshi,Shibata, Norio,Hibino, Motoki,Nagano, Shinichi,Nakamura, Shuichi,Toru, Takeshi
, p. 8521 - 8528 (2007)
The trifluoromethylation of aldehydes and ketones is a potentially powerful method to introduce the CF3 moiety into organic molecules. In general, the trifluoromethylation reaction has been performed by treatment of Me3SiCF3/su
Fe-catalyzed nucleophilic activation of c-si versus allylic C-O bonds: Catalytic trifluoromethylation of carbonyl groups versus tandem trifluormethylation-allylation of olefins
Klein, Johannes E. M. N.,Rommel, Susanne,Plietker, Bernd
supporting information, p. 5802 - 5810 (2015/01/16)
The nucleophilic ferrate salt Bu4N[Fe(CO)3(NO)] (TBA[Fe]) is able to catalyze the direct trifluoromethylation of aldehydes and ketones using Me3SiCF3 as a trifluoromethylating agent. Interception of the C-Si I-b
TTMPP-catalyzed trifluoromethylation of carbonyl compounds and imines with trifluoromethylsilane
Matsukawa, Satoru,Saijo, Marina
, p. 4655 - 4657 (2008/09/21)
A highly basic phosphine, tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP), catalyzes trifluoromethylation using trifluoromethyltrimethylsilane to give the corresponding trifluoromethylated products in good to high yields, with both carbonyl compounds and im
