95123-61-8

Basic information

• Product Name: 2-Propenal, 3-[4-(trifluoromethyl)phenyl]-, (2E)-
• CAS NO: 95123-61-8
• Molecular Formula: C10H7F3O
• Molecular Weight: 200.16
• Mol File: 95123-61-8.mol
• Article Data: 52

Chemical Properties

• CAS DataBase Reference: 2-Propenal, 3-[4-(trifluoromethyl)phenyl]-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenal, 3-[4-(trifluoromethyl)phenyl]-, (2E)-(95123-61-8)
• EPA Substance Registry System: 2-Propenal, 3-[4-(trifluoromethyl)phenyl]-, (2E)-(95123-61-8)

Safety Data

• Hazardous Substances Data: 95123-61-8(Hazardous Substances Data)

Usage

General Description

2-Propenal, 3-[4-(trifluoromethyl)phenyl]-, (2E)- is a chemical compound with the molecular formula C10H7F3O. It is also known as 3-(4-trifluoromethylphenyl)-2-propenal and is classified as an alpha, beta-unsaturated aldehyde. 2-Propenal, 3-[4-(trifluoromethyl)phenyl]-, (2E)- is commonly used in the synthesis of pharmaceuticals and agrochemicals, and also has applications in the production of fragrances and flavorings. It is known to have potential toxic effects and should be handled with care. Additionally,

Upstream product

• 20461-86-3 2,2-diethoxy acetic acid 
• 1059140-27-0 1-(2-bromovinyl)-4-(trifluoromethyl)benzene 
• 83494-26-2 α-ethynyl-4-(trifluoromethyl)-benzenemethanol 
• 201230-82-2 carbon monoxide 
• 705-31-7 4-trifluoromethylphenylacetylene 
• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 75-07-0 acetaldehyde 
• 1813-97-4 1-allyl-4-(trifluoromethyl)benzene 
• 298-12-4 Glyoxilic acid 
• 3054-95-3 acrylaldehyde diethyl acetal 
• 455-13-0 4-Iodobenzotrifluoride 
• 352525-91-8 trans-2-[4-(trifluoromethyl)phenyl]vinylboronic acid 
• 149946-79-2 1-(4'-(trifluoromethyl)phenyl)-allylalcohol 
• 166947-09-7 3-(4-trifluoromethylphenyl)propanal 

Downstream Products

• 1000682-30-3 (2Z,4E)-methyl 2-azido-5-(4-(trifluoromethyl)phenyl)penta-2,4-dienoate 
• 1005470-45-0 3-formyl-2-(4-trifluoromethyl-phenyl)-cyclopent-3-ene-1,1-dicarboxylic acid dimethyl ester 
• 1005773-00-1 (1S,2R,3R,5R)-2-(4-(trifluoromethyl)phenyl)-6-(4-methoxyphenylsulfonyl)-3,5-diphenyl-6-azabicyclo[3.2.0]heptan-7-one 
• 1013421-12-9 methyl 3-(4-methoxyphenylamino)-3-(4-trifluoromethylphenyl)propanoate 
• 1171119-17-7 C₁₅H₁₆F₃NO₃ 
• 1171118-89-0 C₁₅H₁₆F₃NO₃ 
• 1158468-31-5 (1S,6R)-ethyl 3-(diethoxyphosphoryl)-2-oxo-6-(4-(trifluoromethyl)phenyl)cyclohex-3-enecarboxylate 
• 1219359-65-5 (S)-3-formyl-4-methyl-2-(4-(trifluoromethyl)phenyl)cyclopent-3-ene-1,1-dicarbonitrile 

Relevant articles and documents

Crossed Regio- and Enantioselective Iron-Catalyzed [4+2]-Cycloadditions of Unactivated Dienes

The cyclohexene motif is ubiquitous in nature and specialty chemicals. A straightforward selective access to chiral cyclohexenes from unactivated dienes and dienophiles is not feasible by classical Diels–Alder reaction and constitutes an unsolved syntheti

Selective Rhodium-Catalyzed Hydroformylation of Terminal Arylalkynes and Conjugated Enynes to (Poly)enals Enabled by a π-Acceptor Biphosphoramidite Ligand

The hydroformylation of terminal arylalkynes and enynes offers a straightforward synthetic route to the valuable (poly)enals. However, the hydroformylation of terminal alkynes has remained a long-standing challenge. Herein, an efficient and selective Rh-catalyzed hydroformylation of terminal arylalkynes and conjugated enynes has been achieved by using a new stable biphosphoramidite ligand with strong π-acceptor capacity, which affords various important E-(poly)enals in good yields with excellent chemo- and regioselectivity at low temperatures and low syngas pressures.

Asymmetric Synthesis of Functionalized 9-Methyldecalins Using a Diphenylprolinol-Silyl-Ether-Mediated Domino Michael/Aldol Reaction

Substituted 9-methyldecalin derivatives containing an all carbon quaternary chiral center were synthesized with excellent enantioselectivity via an organocatalyst-mediated domino reaction. The first reaction is a diphenylprolinol silyl ether-mediated Michael reaction, and the second reaction is an intramolecular aldol reaction. The enantiomerically pure catalyst is involved in both reactions.