1059140-27-0

Basic information

• Product Name: 1-(2-bromovinyl)-4-(trifluoromethyl)benzene
• Synonyms: 1-(2-bromovinyl)-4-(trifluoromethyl)benzene
• CAS NO: 1059140-27-0
• Molecular Weight: 251.046
• Mol File: 1059140-27-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-(2-bromovinyl)-4-(trifluoromethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-bromovinyl)-4-(trifluoromethyl)benzene(1059140-27-0)
• EPA Substance Registry System: 1-(2-bromovinyl)-4-(trifluoromethyl)benzene(1059140-27-0)

Safety Data

• Hazardous Substances Data: 1059140-27-0(Hazardous Substances Data)

Upstream product

• 402-50-6 1-trifluoromethyl-4-vinyl-benzene 
• 705-31-7 4-trifluoromethylphenylacetylene 
• 1737-26-4 1-(4-trifluorophenyl)ethanol 
• 131356-53-1 1-(2,2-dibromovinyl)-4-(trifluoromethyl)benzeney 
• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 402-51-7 4-(trifluoromethyl)phenylmagnesium bromide 

Downstream Products

• 947700-89-2 C₂₂H₁₇F₃ 
• 115665-78-6 trans-1-(2-bromovinyl)-4-(trifluoromethyl)benzene 
• 1068616-21-6 (E)-(4-trifluoromethylstyryl)(phenyl)sulfane 
• 501003-48-1 9-[(4-trifluoromethylphenyl)methylene]-9H-fluorene 
• 1512864-83-3 (E)-1-methyl-4-((4-(trifluoromethyl)styryl)sulfonyl)benzene 
• 95123-61-8 (2E)-3-(4-trifluoromethylphenyl)prop-2-enal 
• 1027335-55-2 (E)-2-(4-(trifluoromethyl)styryl)pyridine 

Relevant articles and documents

Selective Rhodium-Catalyzed Hydroformylation of Terminal Arylalkynes and Conjugated Enynes to (Poly)enals Enabled by a π-Acceptor Biphosphoramidite Ligand

The hydroformylation of terminal arylalkynes and enynes offers a straightforward synthetic route to the valuable (poly)enals. However, the hydroformylation of terminal alkynes has remained a long-standing challenge. Herein, an efficient and selective Rh-catalyzed hydroformylation of terminal arylalkynes and conjugated enynes has been achieved by using a new stable biphosphoramidite ligand with strong π-acceptor capacity, which affords various important E-(poly)enals in good yields with excellent chemo- and regioselectivity at low temperatures and low syngas pressures.

Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides

A novel reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides has been realized via photoredox/nickel dual catalysis to produce vinyl arene derivatives bearing all-carbon quaternary centers with excellent E-selectivity. A stoichiometric metal reductant could be avoided by employing commercially available N,N,N′,N′-tetramethylethylenediamine (TMEDA) as the terminal reductant.

Ni-catalyzed reductive coupling of α-halocarbonyl derivatives with vinyl bromides

This work describes the vinylation of α-halo carbonyl compounds with vinyl bromides under Ni-catalyzed reductive coupling conditions. While aryl-conjugated vinyl bromides entail pyridine as the sole labile ligand, the alkyl-substituted vinyl bromides require both bipyridine and pyridine as the co-ligands.