95465-72-8

Basic information

• Product Name: 3-(2-METHOXYPHENYL)PROPIOPHENONE
• Synonyms: 3-(2-METHOXYPHENYL)PROPIOPHENONE
• CAS NO: 95465-72-8
• Molecular Formula: C₁₆H₁₆O₂
• Molecular Weight: 240.3
• Mol File: 95465-72-8.mol
• Article Data: 35

Chemical Properties

• Boiling Point: 381.1°C at 760 mmHg
• Flash Point: 167.9°C
• Appearance: /
• Density: 1.081g/cm³
• Vapor Pressure: 5.18E-06mmHg at 25°C
• Refractive Index: 1.562
• CAS DataBase Reference: 3-(2-METHOXYPHENYL)PROPIOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-METHOXYPHENYL)PROPIOPHENONE(95465-72-8)
• EPA Substance Registry System: 3-(2-METHOXYPHENYL)PROPIOPHENONE(95465-72-8)

Safety Data

• Hazardous Substances Data: 95465-72-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C16H16O2/c1-18-16-10-6-5-9-14(16)11-12-15(17)13-7-3-2-4-8-13/h2-10H,11-12H2,1H3

Upstream product

• 5416-70-6 2-methoxychalcone 
• 74-88-4 methyl iodide 
• 22965-99-7 (E)-3-(2-methoxylphenyl)-1-phenylprop-2-en-1-one 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 64-17-5 ethanol 
• 98-86-2 acetophenone 
• 135-02-4 ortho-anisaldehyde 
• 612-16-8 (2-methoxyphenyl)methanol 
• 98-85-1 1-Phenylethanol 
• 936-59-4 3-chloropropiophenone 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 529-28-2 4-iodoanisol 
• 37442-45-8 ethyl 2-(hydroxy(phenyl)methyl)propenoate 
• 612-15-7 o-methoxystyrene 

Downstream Products

• 1353093-44-3 (+/-)-2-(3-methylbenzyl)-2-phenylchroman 
• 1353093-45-4 (+/-)-2-[4-(tert-butyl)benzyl]-2-phenylchroman 
• 1353093-50-1 1-methoxy-2-(3-phenylbut-3-en-1-yl)benzene 
• 93-89-0 benzoic acid ethyl ester 
• 1267112-76-4 1,1,1-trifluoro-4-(2-methoxyphenyl)butan-2-one 
• 1446018-15-0 5-(2-methoxybenzyl)-N-(4-methoxybenzyl)-4-phenylthiazol-2-amine 
• 1446018-19-4 5-(2-methoxybenzyl)-N-(4-methoxyphenyl)-4-phenylthiazol-2-amine 
• 1446018-69-4 C₁₆H₁₅BrO₂ 
• 1225718-66-0 5-(2-methoxybenzyl)-4-phenylthiazol-2-amine 

Relevant articles and documents

Complementary Photocatalytic Toolbox: Control of Intramolecular endo-versus exo-trig Cyclizations of α-Phenyl Olefins to Oxaheterocyclic Products

The regioselectivity of the intramolecular cyclization of bifunctional α-phenyl alkenes can be controlled simply by the choice of the organic chromophore as the photocatalyst. The central photoredox catalytic reaction in both cases is a nucleophilic addition of the hydroxyl function to the olefin function of the substrates. N,N-(4-Diisobutylaminophenyl) phenothiazine catalyzes exo-trig cyclizations, whereas 1,7-dicyanoperylene-3,4,9,10-tetracarboxylic acid bisimides catalyze endo-trig additions to products with anti-Markovnikov regioselectivity. We preliminarily report the photoredox catalytic conversions of 11 representative substrates into 20 oxaheterocycles in order to demonstrate the similarity, but also the complementarity, of these two variants in this photoredox catalytic toolbox.

BTP-Rh@g-C3N4 as an efficient recyclable catalyst for dehydrogenation and borrowing hydrogen reactions

Highly active catalysts play an important role in modern catalysis. A novel and efficient ligand benzotriazole-pyrimidine (BTP) and the corresponding rhodium composite on C3N4 were successfully synthesized. The resulting rhodium composite was fully characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), x-ray diffraction (XRD), thermogravimetric analysis (TGA), and x-ray photoelectron spectroscopy (XPS). The obtained composite exhibited good catalytic activity and good recovery performance in the synthesis of quinoxaline from 2-aminobenzyl alcohol and benzonitrile, and more than 20 quinoxalines were obtained in good yields. Additionally, it also showed that rhodium composite could achieved good catalytic performance in the synthesis of functionalized ketone through borrowing hydrogen strategy.

Synthesis of α-Alkylated Ketones via Selective Epoxide Opening/Alkylation Reactions with Primary Alcohols

A new method for converting terminal epoxides and primary alcohols into α-alkylated ketones under borrowing hydrogen conditions is reported. The procedure involves a one-pot epoxide ring opening and alkylation via primary alcohols in the presence of an N-heterocyclic carbene iridium(I) catalyst, under aerobic conditions, with water as the side product.