96-15-1

Basic information

• Product Name: 2-METHYLBUTYLAMINE
• Synonyms: 2-METHYL-1-BUTYLAMINE;1-AMINO-2-METHYLBUTANE;1-AMINO-3-METHYLBUTANE;RARECHEM AL BW 0193;1-Amino-2-methylbutan;1-Butanamine,2-methyl-;2-methyl-1-butanamin;2-Methyl-1-butanamine
• CAS NO: 96-15-1
• Molecular Formula: C₅H₁₃N
• Molecular Weight: 87.16
• EINECS: 202-483-5
• Product Categories: Anilines, Aromatic Amines and Nitro Compounds
• Mol File: 96-15-1.mol
• Article Data: 12

Chemical Properties

• Melting Point: -70°C (estimate)
• Boiling Point: 94-97 °C(lit.)
• Flash Point: 38 °F
• Appearance: Clear colorless to slightly yellow/Liquid
• Density: 0.738 g/mL at 25 °C(lit.)
• Vapor Pressure: 52.4mmHg at 25°C
• Refractive Index: n20/D 1.4116(lit.)
• Storage Temp.: Flammables area
• Solubility: alcohols and water: soluble(lit.)
• PKA: 10.75±0.10(Predicted)
• BRN: 1718806
• CAS DataBase Reference: 2-METHYLBUTYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYLBUTYLAMINE(96-15-1)
• EPA Substance Registry System: 2-METHYLBUTYLAMINE(96-15-1)

Safety Data

• Hazard Codes: F,C
• Statements: 11-20/21/22-34
• Safety Statements: 16-23-26-36-36/37/39-45
• RIDADR: UN 2733 3/PG 2
• WGK Germany: 3
• HazardClass: 3.1
• PackingGroup: II
• Hazardous Substances Data: 96-15-1(Hazardous Substances Data)

Usage

Chemical Properties

Different sources of media describe the Chemical Properties of 96-15-1 differently. You can refer to the following data:
1. CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
2. Colorless to yellowish liquid; fishy aroma.

Aroma threshold values

High strength odor, fishy type; recommend smelling in a 0.10% solution or less.

InChI:InChI=1/C5H13N/c1-3-5(2)4-6/h5H,3-4,6H2,1-2H3/p+1/t5-/m1/s1

Upstream product

• 1565-80-6 (2S)-2-methyl-1-butanol 
• 4403-61-6 2-methyl-2-butene nitrile 
• 61892-69-1 4-methylisovaleramide 
• 319-78-8 D-Isoleucine 
• 73-32-5 DL-isoleucine 
• 137-32-6 (+/-)-2-methyl-1-butanol 
• 100-10-7 4-dimethylamino-benzaldehyde 
• 107-12-0 propiononitrile 
• 73-32-5 L-isoleucine 
• 106-98-9 1-butylene 
• 201230-82-2 carbon monoxide 
• 73-32-5 L-isoleucine 
• 10422-35-2 1-bromo-2-methyl-butane 
• 7664-41-7 ammonia 

Downstream Products

• 4440-16-8 2-(2-furanylmethylene)-propanedioic acid 
• 35089-69-1 N-nitro-N'-pentyl-guanidine 
• 111029-15-3 1,4-bis-(β-nitro-styryl)-benzene 
• 91338-24-8 N-(2-methyl-butyl)-2,4-dinitro-aniline 
• 102-96-5 (2-nitroethenyl)benzene 
• 1011-92-3 2-cyano-3-phenylacrylic acid 
• 40318-55-6 (3,4-Dimethyl-2,6-dinitro-phenyl)-(2-methyl-butyl)-amine 
• 14618-17-8 N-(2-methylbutyl)-2,2,2-trifluoroacetamide 
• 114284-96-7 (S)-5-Oxo-1-(toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid ((R)-2-methyl-butyl)-amide 
• 114284-95-6 (S)-5-Oxo-1-(toluene-4-sulfonyl)-pyrrolidine-2-carboxylic acid ((S)-2-methyl-butyl)-amide 
• 54449-43-3 N-(2-methylbutyl)benzamide 
• 95-14-7 1,2,3-Benzotriazole 
• 209725-80-4 [6-Benzyloxy-2-(2-methyl-butylamino)-purin-9-yl]-acetic acid 

Relevant articles and documents

DECARBOXYLATION OF AMINO ACIDS. IV.

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Method for preparing primary amine by catalyzing reductive amination of aldehyde ketone compounds

The invention discloses a method for preparing primary amine by catalyzing reductive amination of aldehyde ketone compounds. The method comprises the following steps: 1) mixing nickel nitrate hexahydrate, citric acid and an organic solvent, carrying out heating and stirring until a colloidal material is obtained, drying the colloidal material, roasting the colloidal material in a protective atmosphere, pickling, washing and drying a roasted product, and performing a partial oxidation reaction on a dried product in an oxygen-nitrogen mixed atmosphere to obtain a catalyst for a reductive amination reaction; and 2) mixing aldehyde or ketone compounds, a methanol solution of ammonia and the reductive amination reaction catalyst, introducing hydrogen, and carrying out a reductive amination reaction. The method has the advantages of high primary amine yield, high selectivity, wide aldehyde ketone substrate range, short reaction time, mild reaction conditions, low cost, greenness, economicalperformance and the like; the used reductive amination reaction catalyst can be recycled more than 10 times, and the catalytic activity of the catalyst is not obviously changed in gram-level reactions; and the method is suitable for large-scale application.

Amination of aliphatic alcohols with urea catalyzed by ruthenium complexes: effect of supporting ligands

In the present study, ruthenium-catalyzed amination of alcohols by urea as a convenient ammonia carrier in the presence of free diphosphine ligands has been described. A number of ruthenium-phosphine complexes have been studied among which, [(Cp)RuCl(dppe)] was found as an efficient catalyst for alcohol amination reaction. The crystal structures of two new half-sandwich ruthenium complexes, [(Cp)RuCl(dppe)] and [(C6H6)RuCl2(PHEt2)], were determined by X-ray crystallographic analysis. Also the effect of using different supporting phosphines, ratio of raw materials and reaction temperature on conversion and selectivity was investigated. Under optimum reaction conditions high conversion (98percent) and chemo-selectivity toward secondary amines were obtained.