97399-03-6

Basic information

• Product Name: Silane, [(phenylsulfonyl)methylene]bis[trimethyl-
• CAS NO: 97399-03-6
• Molecular Formula: C13H24O2SSi2
• Molecular Weight: 300.569
• Mol File: 97399-03-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, [(phenylsulfonyl)methylene]bis[trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(phenylsulfonyl)methylene]bis[trimethyl-(97399-03-6)
• EPA Substance Registry System: Silane, [(phenylsulfonyl)methylene]bis[trimethyl-(97399-03-6)

Safety Data

• Hazardous Substances Data: 97399-03-6(Hazardous Substances Data)

Upstream product

• 3112-85-4 methylphenylsulfonate 
• 75-77-4 chloro-trimethyl-silane 
• 17872-92-3 (phenylsulfonylmethyl)trimethylsilane 
• 62761-90-4 α,α-bis(trimethylsilyl)methylphenyl sulfide 

Downstream Products

• 125951-06-6 (E)-4-[2-(phenylsulfonyl)vinyl]benzonitrile 
• 125951-13-5 (E)-methyl 4-(2-(phenylsulfonyl)vinyl)benzoate 
• 64329-88-0 (E)-((2-phenylprop-1-en-1-yl)sulfonyl)benzene 
• 90020-44-3 (cyclohexylidene)methyl phenyl sulfone 
• 93039-32-8 [Benzenesulfonyl-(2,3-diphenyl-cycloprop-2-enylidene)-methyl]-trimethyl-silane 
• 26189-62-8 phenyl 2,2-diphenylethenyl sulfone 

Relevant articles and documents

Sulfone reagents in organic synthesis. VI. Sulfonyl- and silyl-substituted hydrocarbons as versatile carbanion precursors in organic synthesis

The basic organometallic chemistry of β-silyl-substituted acetylenic, vinylic and alkyl sulfones has been investigated, with attention being given to metallation, carbometallation and the chemical reduction of carbon-carbon unsaturation. 2-Trimethylsilylvinyl and 2-trimethylsilylalkyl sulfones underwent smooth and stereoselective lithiation with RLi on the carbon α to the sulfonyl group. Carbometallation of vinyl sulfones could be achieved with RMgX or LiCuR2, but acetylenic sulfones carbometallated smoothly only with LiCuR2; with RMgX or RLi, these acetylenes underwent alkyldesulfonylation. The utility in synthesis of these metallo derivatives of sulfonyl-silyl-hydrocarbons is discussed and their value in elaborating carbon skeletons is illustrated for the preparation of alkenes, allenes, carbocycles and stereo-defined vinyl sulfones.