26189-62-8Relevant articles and documents
Synthesis of Sulfonated Benzo[d][1,3]oxazines by Merging Photoredox Catalysis and Insertion of Sulfur Dioxide
Liu, Tong,Zheng, Danqing,Li, Zhenhua,Wu, Jie
, p. 865 - 869 (2018)
A photocatalytic reaction of N-(2-vinylphenyl)amides, DABCO?(SO2)2 and arenediazonium tetrafluoroborates for the synthesis of 4-((arylsulfonyl)methyl)-4H-benzo[d][1,3]oxazines under mild conditions is reported. This synthetic approac
Metal-Free Visible-Light Photocatalytic Tandem Radical Addition–Cyclization Strategy for the Synthesis of Sulfonyl-Containing Isoquinolinediones
Zuo, Kai-Li,He, Yan-Hong,Guan, Zhi
, p. 939 - 948 (2019)
A mild radical cascade reaction for the synthesis of sulfonyl-containing isoquinolinediones has been developed, in which sulfonyl radicals can be accessed from simple sodium sulfinates under visible light and eosin Y catalysis. This tandem approach features a broad range of substrates and functional group tolerance. With this strategy, trifluoromethylated isoquinolinedione was also obtained.
HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents
Ryabukhin, Dmitry S.,Vasilyev, Aleksander V.
, p. 500 - 501 (2016)
Arylacetylenes, conjugated with electron-withdrawing groups, ArC[tbnd6]C(EWG) [EWG = SO2Ph, PO(OEt)2, COMe, CO2Me] in reaction with benzene at room temperature or 130?°C (glass high pressure tube) for 1–10?h under the acti
Light-Mediated Difluoromethylthiolation of Aldehydes with a Hydrogen Atom Transfer Photocatalyst
Dong, Jianyang,Yue, Fuyang,Wang, Xiaochen,Song, Hongjian,Liu, Yuxiu,Wang, Qingmin
, p. 8272 - 8277 (2020)
A mild general method for difluoromethylthiolation of aldehydes with PhSO2SCF2H and a decatungstate photocatalyst under redox-neutral conditions has been developed. This reaction is highly efficient, scalable, and oxidant-free. The broad substrate scope and excellent functional group tolerance of the reaction make it suitable for generating libraries of difluoromethyl thioesters. We demonstrated the utility and sustainability of the method by synthesizing several structurally complex difluoromethyl thioesters.
Electrochemistry Enabled Nickel-Catalyzed Selective C?S Bond Coupling Reaction
Pan, Yi,Wang, Yang,Wang, Yi,Zhang, Feng
, (2022/02/16)
This work describes an electrochemical enabled nickel-catalyzed chemoselective C?S bond coupling protocol for the production of aryl sulfides and sulfones. By simply switching the nickel catalysts and electrodes, this electrochemical C?S bond coupling has demonstrated excellent redox activity, scalability and sustainability. Furthermore, the mechanism for this electrochemical cross-coupling reaction has been investigated.
Visible-Light-Triggered Sulfonylation/Aryl Migration/Desulfonylation and C-S/Se Bond Formation Reaction: 1,2,4-Trifunctionalization of Butenyl Benzothiazole Sulfone with Thiosulfonate/Selenosulfonates
Liu, Xin-Yu,Tian, Shi-Yin,Jiang, Yi-Fan,Rao, Weidong,Wang, Shun-Yi
supporting information, p. 8246 - 8251 (2021/11/01)
A visible-light-triggered radical cascade sulfonylation/aryl migration/desulfonylation and C-S/Se bond formation reaction of butenyl benzothiazole sulfone with thiosulfonates or selenosulfonates is developed. This study affords the 1,2,4-trifunctionalization of butenyl benzothiazole sulfone derivatives under mild conditions.