97723-86-9Relevant articles and documents
Fe-catalyzed thioesterification of carboxylic esters
Magens, Silja,Plietker, Bernd
supporting information; experimental part, p. 8807 - 8809 (2011/09/16)
Second nature: Starting from shelf-stable aryl esters and thiols, a variety of carboxylic acid esters were transformed into the corresponding thioesters with no racemization of labile stereocenters (see scheme). The method was successfully applied in a native chemical-ligation-type peptide formation, which suggests that the thiol may act as a co-catalyst for future 1,2-additions of pronucleophiles to carboxylic esters.
A New and Efficient Method for the Preparation of S-Phenyl Carbothioates via Mixed Anhydrides Using Active Titanium(IV) Salts
Mukaiyama, Teruaki,Miyashita, Mitsutomo,Shiina,, Isamu
, p. 1747 - 1750 (2007/10/02)
In the presence of a catalytic amount of titanium(IV) salt, various S-phenyl carbothioates are prepared in excallent yields by the reaction of nearly equimolar amounts of silyl derivatives of carboxylic acids and benzenethiols with p-trifluoromethylbenzoic anhydride.
