99512-11-5

Basic information

• Product Name: (E)‐4‐(4'‐methoxyphenyl)but‐3‐en‐2‐yl acetate
• Synonyms: (E)‐4‐(4'‐methoxyphenyl)but‐3‐en‐2‐yl acetate
• CAS NO: 99512-11-5
• Molecular Weight: 220.268
• Mol File: 99512-11-5.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (E)‐4‐(4'‐methoxyphenyl)but‐3‐en‐2‐yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)‐4‐(4'‐methoxyphenyl)but‐3‐en‐2‐yl acetate(99512-11-5)
• EPA Substance Registry System: (E)‐4‐(4'‐methoxyphenyl)but‐3‐en‐2‐yl acetate(99512-11-5)

Safety Data

• Hazardous Substances Data: 99512-11-5(Hazardous Substances Data)

Upstream product

• 32271-54-8 (E)-1-(4-methoxyphenyl)pent-1-en-3-ol 
• 75-36-5 acetyl chloride 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 140846-38-4 (E)-1-(4-methoxyphenyl)-2-buten-1-ol 
• 108-24-7 acetic anhydride 
• 123-11-5 4-methoxy-benzaldehyde 
• 3179-10-0 (E)-1-methoxy-4-(2-nitrovinyl)benzene 
• 141-78-6 ethyl acetate 

Downstream Products

• 1380438-72-1 (-)-(S)-(E)-4-(4-methoxyphenyl)but-3-en-2-yl acetate 
• 1380438-78-7 (-)-(R)-(E)-3-(4-(4-methoxyphenyl)but-3-en-2-yl)furan-2(5H)-one 
• 1587713-35-6 (Z)-4-(4-(4-methoxyphenyl)but-3-en-2-yl)morpholine 
• 1587713-39-0 (Z)-N-(4-(4-methoxyphenyl)but-3-en-2-yl)cyclohexanamine 
• 1587713-17-4 (E)-4-(4-(4-methoxyphenyl)but-3-en-2-yl)morpholine 
• 1587713-21-0 (E)-N-(4-(4-methoxyphenyl)but-3-en-2-yl)cyclohexanamine 
• 30448-78-3 p-methoxyphenylbutadiene 

Relevant articles and documents

Free and immobilized lecitase ultra as the biocatalyst in the kinetic resolution of (E)‐4‐arylbut‐3‐en‐2‐yl esters

The influence of buffer type, co‐solvent type, and acyl chain length was investigated for the enantioselective hydrolysis of racemic 4‐arylbut‐3‐en‐2‐yl esters using Lecitase Ultra (LU). Immobilized preparations of the Lecitase Ultra enzyme had

Catalytic stereospecific allyl-allyl cross-coupling of internal allyl electrophiles with allylB(pin)

Application of internal electrophiles in catalytic stereospecific allyl-allyl cross-coupling enable the rapid construction of multisubstituted 1,5-dienes, including those with all carbon quaternary centers. Compounds with minimal steric differentiation ca

Highly enantioselective synthesis of 3-substituted furanones by palladium-catalyzed kinetic resolution of unsymmetrical allyl acetates

Resolving the issue: A near-perfect Pd-catalyzed kinetic resolution of 1,3-disubstituted unsymmetrical allylic acetates uses silyl enol ethers as nucleophiles to access the important 3-substituted-furanone scaffold (see scheme; DACH=diaminocyclohexyl, dba=dibenzylideneacetone). The reaction proceeds under mild conditions and provides the desired products with excellent chemo-, regio-, and enantioselectivity. Copyright