30448-78-3

Basic information

• Product Name: Benzene, 1-(1,3-butadienyl)-4-methoxy-
• CAS NO: 30448-78-3
• Molecular Formula: C11H12O
• Molecular Weight: 160.216
• Mol File: 30448-78-3.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1,3-butadienyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1,3-butadienyl)-4-methoxy-(30448-78-3)
• EPA Substance Registry System: Benzene, 1-(1,3-butadienyl)-4-methoxy-(30448-78-3)

Safety Data

• Hazardous Substances Data: 30448-78-3(Hazardous Substances Data)

Upstream product

• 24680-50-0 4-methoxy-trans-cinnamaldehyde 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 52220-42-5 1-((E)-4-Chloro-but-2-enyl)-4-methoxy-benzene 
• 140-67-0 Estragole 
• 768-60-5 4-methoxyphenylacetylen 
• 1963-36-6 4-methoxycinnamaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 97852-37-4 2-(4-methoxyphenyl)-3-vinyloxirane 
• 1560-54-9 allyltriphenylphosphonium bromide 
• 24165-60-4 1-(4-methoxyphenyl)but-3-en-1-ol 
• 140846-38-4 (E)-1-(4-methoxyphenyl)-2-buten-1-ol 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 99512-11-5 (E)‐4‐(4'‐methoxyphenyl)but‐3‐en‐2‐yl acetate 

Relevant articles and documents

Crossed Regio- and Enantioselective Iron-Catalyzed [4+2]-Cycloadditions of Unactivated Dienes

The cyclohexene motif is ubiquitous in nature and specialty chemicals. A straightforward selective access to chiral cyclohexenes from unactivated dienes and dienophiles is not feasible by classical Diels–Alder reaction and constitutes an unsolved syntheti

Asymmetric Counteranion Directed Catalytic Heck/Tsuji-Trost Annulation of Aryl Iodides and 1,3-Dienes

A chiral anion-mediated asymmetric Heck/Tsuji-Trost reaction of aryl iodides and 1,3-dienes is presented. Chiral indoline derivatives could be afforded with remarkably higher yields and enantioselectivities than our previous chiral ligand-based method. Silver carbonate is employed as both base and halide scavenger to ensure fast and recyclable exchange of the catalytic amount of chiral anions. Fast salt metathesis, as well as the acceleration effect of the chiral anion, could both benefit the stereocontrol of the reaction.

Photoinduced Palladium-Catalyzed Carbofunctionalization of Conjugated Dienes Proceeding via Radical-Polar Crossover Scenario: 1,2-Aminoalkylation and beyond

A photoinduced palladium-catalyzed 1,2-carbofunctionalization of conjugated dienes has been developed. This mild modular approach, which does not require employment of exogeneous photosensitizers and external oxidants, allows for efficient and highly regio- and stereoselective synthesis of a broad range of allylic amines from readily available 1,3-dienes, alkyl iodides, and amines. Employment of O- and C-nucleophiles toward oxyalkylation and dialkylation products was also demonstrated. A putative π-allyl palladium radical-polar crossover path is proposed as a key event in this three-component coupling process. The utility of this protocol is highlighted by its application for derivatization of several amine-containing drugs.